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    20 September 2005, Volume 11 Issue 3
    Article
    Spatial and Temporal Distribution and Characteristics of Granitoids in the Gangdese, Tibet and Implication for Crustal Growth and Evolution
    MO Xuan-xue1 2, DONG Guo-chen2, ZHAO Zhi-dan1 2, ZHOU Su1 2, WANG Liang-liang2, QIU Rui-zhao3, ZHANG Feng-qin2
    2005, 11(3):  281-290. 
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    Granites are important components in the continents, and also closely related to mineral resources. Granites take c. 12% of the total area of Tibetan territory and about 80% (in area) of them are distributed in the Gangdese magmatic belt. Spatially, the Gangdese granitoid belt consists of three zones, i. e. , north, middle and south zones, as a result of the evolution of Neo-Tethyan Bangong Co-Nujiang ocean and Yarlung Zangbo Ocean. Temporally, the tectono-magmatie events in the Tibetan Plateau and the Gangdese can be divided into three stages: Pre-collisional ( 〉65 Ma), syn-collisional (65 -45 Ma) and post-collisional ( 〈 45Ma). Nd and Sr isotopes of granitoids in the Gangdese provide a hint for understanding the crust growth and evolution. Most of granites in southern Gangdese have positive values of εNd (t) ( + 1. 64 - + 5.21 ) and young Nd model ages tDM ( 〈500 Ma), showing characteristics of the juvenile crust. It implies that the mantle material played a significant role in granite petrogenesis. Granites in middle and northern Gangdese, however, are characterized by negative εNd(t) ( -5.3 - - 17.3) and relatively older tDM, 1. 2 Ga and 2.0 - 2.5 Ga, implying a Neo- and Paleo-Proterozoic basement. Crustal material played a major role in granite petrogenesis for the latter case.
    Metallogeneses and Their Geodynamic Settings Related to Mesozoic Granitoids in the Nanling Range
    Hua Ren-min, Chen Pei-rong, Zhang Wen-lan, Yao Jun-ming, Lin Jin-fu, Zhang Zhan-shi, Gu Sheng-yan
    2005, 11(3):  291-304. 
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    Affected by the compressive stress from the Indo-China Peninsula, the Indosinian Orogenesis, characterized by collision, thrust and uplifting, took place inside the South China plate the Indosinian granitoids in the Nanling Range and vicinity areas are mostly of during 250 -230 Ma. The ages of 240 -205 Ma, indicating that they were emplaced in both syn-collision and post-collision geodynamic settings. No important granite-related metallogeneses occurred in this duration. A post-orogeny setting started from the beginning of the Yanshanian Period, which controlled the large-scale granitic magmatism and related metallogeneses. This paper makes the first attempt to divide the Yanshanian Period into three sub-periods, i.e. the Early, Middle and Late Yanshanian Periods, based on the metallogenic features of granitoids and their geodynamic backgrounds. The magmatic association of the Early Yanshanian Period (about 185 - 170 Ma)comprises four categories of magmafism, i. e. basalt, bimodal volcanics, A-type granite, and the intra-plate high-K calc-alkaline, which indicates the beginning of extensionthinning of lithosphere and upwelling of mantle material in a relative small and local extent. Pb-Zn, Cu, and Au mineralization associated with high-K calc-alkaline magmatism represents the metallogeny of this period. During the Middle Yanshanian Period, lithospheric extending-thinning developed more widely and intensively, and hence the mantle upwelling and basaltic magma underplating, which caused the formation of great amount of crust re-melting granitoids. This period can further be divided into two stages. The first stage ( 170 - 150 Ma) is represented by large-scale emplacement of crust re-melting granites with some tungsten mineralization at the end. The second stage ( 150 - 140 Ma) is the most important time of large-scale mineralizations of non-ferrous and rare metals, e.g. W, Sn, Nb-Ta, Bi, Mo, Be, in the Nanling Range area, although much less granitoid developed. The Late Yanshanian Period (140 -65 Ma) was generally characterized by full extension and breakup of the lithosphere of South China. However, owing to the influence of Pacific plate movement, the eastern part of South China was predominated by subduction-related compression, which resulted in magmatism of calc-alkaline and shoshonite series and related metallogeneses of Au, Ag, Pb-Zn, Cu, (Mo, Sn) , followed by extension in late stage. In the Nanling Range area, Late Yanshanian magmatism was represented by emplacement of granitic volcanic-intrusive complexes which were genetically related to volcanic-type uranium and porphyry type tin deposits, as well as mafic dykes which caused the mobilization, transportation and mineralization of uranium in pre-existing Indosinian granites.
    Geochronological Framework of the Mesozoic Granitic Magmatism in the Liaodong Peninsula, Northeast China
    WU Fu-yuan1, YANG Jin-hui1, LIU Xiao-ming2
    2005, 11(3):  305-317. 
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    Liaodong Peninsula, located in the northeastern part of the North China Craton (NCC), is one of the important areas where the Mesozoic granitoid rocks are widely distributed. It is traditionally thought that the granitoids in this area were mainly emplaced during Triassic to early-middle Jurassic. In this paper, more than 60 samples of zircons have been run for U-Pb geochronological dating using SHRIMP, TIMS and LA-ICPMS techniques. Based on these new data, three stages of granitic magmatism are identified: Triassic (233 -212 Ma), Jurassic (180- 156 Ma) and Early Cretaceous (131 - 117 Ma). The Triassic plutons include alkaline syenite (Saima- Bolinchuan), dolerite, diorite and monzogranite. The Jurassic granites are characterized by ductile deformation and a lot of inherited zircons. Some plutons of this stage were considered as Archean tonalite and Proterozoic intrusions or migmatites. The Early Cretaceous intrusions are consisted of numerous rock types, including dolerite, diorite, monzonite, porphyritic granite, highly fractionated alkali feldspar granite and A-type granite, and occurred usually as large batholiths. Magma mixing is extensively developed between the diorite and granite. The major difference from the previous thought after throughout geochronological analyses is that the early Cretaceous is the most important period of granitic magmatism in this area. Comprehensive comparisons with granitoids in other areas of the NCC, it is found that the Triassic-Jurassic granitoids are mostly exposed in the eastern part of the NCC, whereas the Early Cretaceous granitoids are developed in all areas. This geochronological framework provides important informa- tion to constrain the Mesozoic tectonic evolution of the NCC.
    Late Mesozoic - Cenozoic Basaltic Rocks and Crust-Mantle Interaction, SE China
    XU Xi-sheng, XlE Xin
    2005, 11(3):  318-334. 
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    There are few volcanic activities during early Mesozoic in SE China. Late Mesozoic large scale volcanic magmatism started from middle Jurassic, continued for a duration of 100 Ma and became most intensive in early Cretaceous, resulting in formation of widely distributed late Mesozoic volcanic-intrusive rocks in this region. Cenozoic magmatism is shown by small scale basaltic magma eruptions along the coast. Three volcanic belts are studied in this paper, which include a nearly east-west (EW) trending late Mesozoic volcanic belt distributed across south Hunan, south Jiangxi and southwest Fujian, a nearly north-northeast (NNE) trending late Mesozoic volcanic belt distributed in Zhejiang and east Fujian, and a nearly NNE trending Cenozoic volcanic belt overlies on NNE trending late Mesozoic volcanic belt. By comparison of the geochemical characteristics of basalts from the three volcanic belts, integrating their temporal and spatial distributions, the geneses of the magmas and related crust-mantle interactions as well as the tectonic settings are discussed. Along the nearly EW trending volcanic belt from inland toward coast, the lithology of basalts changes from alkaline to tholeiitic, and the amount of erupted volcanic rocks and the proportions of rhyolites coexisting with the basalts increase. This episode (180 - 170 Ma) of magmatism, formed in within-plate tectonic setting, is the incipi- ence of large-scale late Mesozoic magmatism in SE China and an indicator of conversion from EW strike Tethys tectonic system to NNE strike Pacific tectonic system. The geochemical studies of the basalts indicate crustal contamination increases from the inland to the coast along the volcanic belt, and therefore show different degrees of crustmantle interactions. The nearly NNE trending volcanic belt is dominated by rhyolites and coexisted with minor amount of andesites and basalts. The volume proportion of basalts is less than 30% even in bimodal volcanic rocks. The basalts are mainly of calc-alkaline series rather than tholeiites. Their geochemical characteristics show their formation in island arc tectonic setting. This episode (130 -90 Ma) of magmatism is the climax of large scale volcanic magmatism in SE China constrained by Pacific dynamic system. Extensive crust-mantle interaction was reflected by higher degree of crustal contamination of basalts, and formation of andesitic rocks due to magma mixing between underplating basaltic magma and overlying acidic magma generated from partial melting of crust. The nearly NNE trending Cenozoic volcanic beltis, distributed in the coastal area of Zhejiang and Fujian provinces and dominated by alkali basalts bearing a large amount of mantle xenoliths. Their occurrence is constrained by a series of NNE trending faults of continental margin. Their geochemical signatures show their for mation in typical rifting rifting tectonic setting and therefore their occurrence is an indicator of a turn from island arc tectonic setting into tectonic setting of continental margin. These Cenozoic basalts were generated from asthenospheric mantle and accompanied by an EMII component, but had no obvious crustal contamination.
    Zircon SHRIMP U-Pb Geochronology, Petrology and Geochemistry of the Zhujianshui Granite, Qitianling Pluton, Southern Hunan Province
    ZHU Jin-chu1, ZHANG Hui2, XIE Cai-fu1 3, ZHANG Pei-hua1, YANG Ce1
    2005, 11(3):  335-342. 
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    The Zhujianshui granite of Qitianling pluton is one of the granites whose emplacement age was determined isotopically by biotite K-Ar method during the early 1960's. Since then the Qitianling granitic pluton was considered to be Indosinian (Triassic) for many years. This paper studies the zircon SHRIMP U-Pb geochronology, petrology and geochemistry of the Zhujianshui granite, Qitianling pluton. An emplacement age of 160 ± 2 Ma was obtained which indicates an early Yanshanian (Jurassic) magmatic activity. The Zhujianshui granite is enriched in alkalies ( especially in K), LILE's and HFSE's, and has a mantle-crustal mixed source. It was formed under a postorogenic extensional environment within the South China continent.
    The Products of Partial Melting of the Lower Crust: Origin of Early Yanshanian Lapu Monzogranite, Guangdong Province
    Liu Chang-shi, Chen Xiao-ming, Wang Ru-cheng, Zhang Ai-cheng, Hu Huan
    2005, 11(3):  343-357. 
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    Exposed at the south of Conghua city, Guangdong province, the Lapu amphibole- and biotite-bearing monzonitic granite occupies an area of about 500 km2. The rock is composed of calcic amphibole (0.5%), biotite ( 11 - 13% ), plagioclase (An35 -41,29 -31% ), cryptoperthite (24 -31% ) and quartz (36 -37% ), carrying some amounts of Ca-, Ti-rich minor minerals such as allanite and titanite. Based on zircon U-Pb isotopic dating, the rock emplaced at 163 ±2 Ma (mid-Jurassic). Petrochemically, the Lapu granite is weakly peraluminous (A/ NKC = 1. 043 in average) and with higher K20 content (4.72% in average), belonging to the high-K calcic-alkaline series. The rock has high EREE contents (( 180 -460) × 10-6), showing an evident LREE-enriched and HREE-depleted tendency, and with higher (La/Yb)N values (19 in average). These features indicate that partial melting of source materials for forming Lapu magma occurred at a deeper ( lower crust) level (p 〉 10 × l0s Pa) and that garnet would be a main residual phase, which resulted in HREE depletion in the melt. According to many trac- ers for source rocks (Patino Douce, 1999), it is suggested that the source rocks for forming Lapu magma were metagreywakes or meta-amphibolites. Analyses for Sr, Nd, Pb isotopic compositions of the Lapu granite yielded a feebly high Isr (0.7124 - 0.7155 ) and lower εNd (t) values ( - 11. 18 - - 11. 54 ). Model calculation shows that the melt formed by 55% partial melting of the lower crust rocks would have the similar geochemical features as those of real Lapu granite magma.
    Relation Between the Granite Series and Types, Strontium Isotope Compositions and Isobaths of Moho Surface in South China: Distirbution of Granite Series/Types Restricted the Analysis of Strontium Isotopic Tendency Surface and the Depth Variation of Moho Surface
    WANG Lian-kui1, WANG Qian-shen2, XU Wen-xin1, CHEN Gen-wen1, ZHANG Shao-li1
    2005, 11(3):  358-363. 
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    Based on the mapping of the granitic series and types, strontium isotopic trend surface analyses and isobaths of Moho surface, the deep-level sourced Yangtze series ( series Ⅱ ) granitoids are mainly distributed in the eastern part of South China. The shallow-level sourced Nanling series ( series I ) granitoids are mainly distributed in the central and western parts of South China. The Ningwu type ( type Ⅱ 1 ), Dexing type ( type Ⅱ 2 ) and Fujing-Zhejiang cosatal type ( type Ⅱ3 ) granitoids are distributed in the middle-western, central-eastern and southeastern coastal parts of South China, respectively. The Zhuguangshan type ( type I 1 ), Darongshan type ( type I 2 ) and Guangdimiao type (type I 3 ) granitoeds are distributed in the central, western and northwestern parts of South China, respectively. The generation of granitoids is in close relation with the uplift or depression of the mantle ( Moho surface). The deep-level sourced granitoids (series Ⅱ ) , especially Ⅱ1,Ⅱ 3 types mainly occur in the uplift areas of the mantle, and shallow-level sourced granitiods ( series I ), especially I 2, I 3 type granitoids, mainly occur in the depression areas of the mantle.
    Zircon U-Pb Age, Element and Oxygen Isotope Geochemisty of Neoproterozoic Granites at Shiershan in South Anhui Province
    WU Rong-xin, ZHENG Yong-fei, WU Yuan-bao
    2005, 11(3):  364-382. 
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    Zircon U-Pb dating, whole-rock elements and Sr-Nd isotopes, and mineral O isotope analyses were carried out for Neoproterozoic granites at Shiershan in South Anhui Province. Zircon U-Pb dating indicates two age phases of magmatic zircons formed at 777 ± 9 Ma and 827 ± 15 Ma, respectively. As a whole the granites are characterized by high SiO2 (74.7 - 78.5% ), high K2O (3.99 - 5.64% ), high K2O/Na2O ratios ( 1.5 - 3.0) and very low contents of mafic components ∑TiO2 + Fe2O3^T + MgO ( 1.2 - 3.0% ), showing the features of highly evolved crust. They have similar REE patterns showing LREE-enrichment and strong negative Eu anomalies (Eu/Eu* = 0.2 -0.4). The nearly neutral whole-rock εNd (t) values of- 0.53 to +0.72 indicate a magraatic source with significant proportions of depleted mantle component. The δ^180 values of zircon range from 2.4‰ to 7.1‰, indicating the granites at Shiershan are low δ^18O magmatic rocks; The big variation of δ^18O values reflects their genesis was related to supersolidus hydrothermal alteration. Compared with zircon, the other mineral separates yield considerable variation of δ^18O values, suggesting they suffered different degrees of hydrothermal alteration. On the basis of element and isotope results, we interpret the zircons of 827 ± 15 Ma as of the inherited one, and those of 777 ± 9 Ma as the coeval magmatic genesis. It is inferred that an extensive mantle-derived magmatic activity took place at ca. 1 100 to 880 Ma, and a juvenile crust was formed in the southeastern margin of the Yan- gtze craton. It is assumed that due to anomalous thermal pulse by a mantle superplume event at ca. 827 Ma that heated the overlying lithosphere, the igneous rocks were generated by remelting of the juvenile crust in the thickened orogenic crust. Accompanying rapid opening of the rift, mantle-derived magma moved upward at ea. 780 Ma along the rift zone, resulting in high-T meteorie-hydrothermal alteration within the rift teetonie zone in the level of middle-upper erust, and voluminous volcanic rocks were formed during this period. Due to different degrees of water-rock reaction at high temperature, altered wallrocks of magma chamber within the rifling zone have differently low δ^18O values. At ca. 800℃ the altered wallroeks began to be melted, and almost synchronously emplaced and cooled to form granites. Most old inherited zircons were resorbed, a great deal of magmatic zircons were crystallized at ca. 777 Ma. Because of a very short duration of the melt phase, the granitoid magma could not be uniformized, consequently the granites with differently low δ^18O values were generated. The granites at Shiershan suffered at least two phases of partial melting processes, thus they have the features of highly evolved crust characterized by high SiO2, high K20, and low contents of mafic component.
    Zircon SIMS U-Pb Geochronology of Host Granitoids in Wushan and Yongping Copper Deposits, Jiangxi Province
    DING Xin, JIANG Shao-yong, NI Pei, GU Lian-xing, JIANG Yao-hui
    2005, 11(3):  383-389. 
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    Wushan and Yongping deposits are two of the most important copper deposits in the Lower Yangtz Mineralization Belt. In this study, SIMS U-Pb dating was performed on zircons from host granitoids in both Wushan and Yongping deposits, Jiangxi province. Zircons from both Wushan and Yongping deposits yield two distinct age groups. In Wushan deposit the zircon ages are 145 ±4 Ma and 121 ±3 Ma. In Yongping deposit the zircon ages are 160 ±2 Ma and 135 ±7 Ma. The zircons of earlier stage were likely formed during emplacement of intrusion, and the later ones formed during the later magmatic evolution and/or hydrothermal alteration. We suggest that the granitic magma intrusion ages of Wushan and Yongping deposits are 145 ±4 Ma and 160 ±2 Ma, respectively. These ages also represent the ore forming age for both skaru and porphyry ores that related to the intrusions of Yanshanian magmatism in these two deposits.
    Contrasting Accessory Mineral Assemblages in the Taohuadao Peralkaline and Putuoshan Aluminous A-type Granites, Zhejiang Province
    XlE Lei, WANG Ru-cheng, WANG De-zi, Qiu Jian-sheng
    2005, 11(3):  390-403. 
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    Two typical East China's coastal perakaline and aluminous A-type granites are developed in Taohuadao and Putuoshan of Zhejiang Province, respectively. disfinction. Detailed electron-microprobe analyses are different. The Taohuadao's contains abundant Their geochemistry and main rock-forming minerals show a clear reveal that accessory minerals from these two granite subgroups zircons, allanite, chevkinite and Fe-Ti minerals (titanomagnetite,ilmenite and pyrophanite). By contrast, in the Putuoshan' s, the accessory-mineral assemblage is Th-poor zoned zircon, Ce-monazite and Fe-Ti oxide minerals dominated by magnetite, rutile and pyrophanite. Besides, these two granites could also be defined by internal structure and chemical composition of accessory minerals, especially zircon. Based on the above-mentioned features of accessory minerals, differences in origins, crystallization environments and physicochemical properties between these two granites could thus be inferred. Firstly, Th-rich zircon indicates a relatively high-temperature, Th-rich and deep-sourced magma for the peralkaline granites. Secondly, the presence of magnetite and ruffle suggests the high fo2 during the crystallization of aluminous A-type granite. Thirdly, the occurrence of allanite or Ce-monazite shows the differences of the alkaline index and P2O5 activity between the peralkaline and aluminous A-type magmas.
    Comparative Investigations of A-type Granites in the Coastal and the Nanling Inland Areas of SE China, and Their Tectonic Significances
    HU Jian, QlU Jian-sheng, WANG De-zi, Wang Ru-cheng, ZHANG Xiao-lin
    2005, 11(3):  404-414. 
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    The Mesozoic A-type granites are widely developed in southeastern China. Spatially, they can be further distinguished into the coastal area zone and the Nanling inland area zone. A-type granites in the coastal area zone were formed mainly in Late Cretaceous (92 - 103 Ma), while those in the Nanling inland area zone were generated initially in Early Jurassic and lasted till Early Cretaceous ( 186 - 124 Ma), thus has a long time duration for their formation. Lithologically, A-type granites in the coastal area zone can be further divided into peralkaline and aluminous s ps, while those in the Nanling inland area zone are predominantly of aluminous subgroup. Compared with the A-type granites in the Nanling inland area zone, those in the coastal area zone have more enriched SiO2, Na20 contents, and lower K20, Rb, Sr, Ba concentrations and FeO*/(FeO* +MgO) ratios. Nd, Sr isotope tracing indicates that A-type granites in both zones were crystallized from highly evolved magmas, which were originally generated by mixing of crustal materials with variable amounts of mantle components due to different extension degrees in different regions. Integrated investigations on their rock associations and tectonic settings suggest that Atype granites in the coastal area zone were formed in a back-arc extension environment that related to the westward subduction of the Palaeo-Pacific plate beneath the Eurasia plate, while those in the Nanling inland area zone were generated mainly under a within-plate rift setting, which might be jointly constrained by the Tethyan and the Paleopacific tectonic dynamic systems.
    Volcanic Ash in the Clay Rocks from Upper Shaximiao Formation of Middle Jurassic, Northeast of Sichuan Basin: Evidence from Petrology, Mineralogy and Geochemistry
    ZHANG Chao1, MA Chang-qian1, SHE Zhen-bing2, YIN Kun-long3
    2005, 11(3):  415-424. 
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    The gray montmorillenite-rich beds (clay rocks), discovered in the Upper Shaximiao formation of Middle Jurassic, Wanzhou City, were studied mineralogically and chemically. The clay minerals in the clay rocks are typically montmorillonite, illite and chlorite. Based on the comparison with post-Archean Australian shale (PAAS), north American average shale ( NASC), background value of earth crust clay and other typical rocks, the studied clay rocks are characterized by low abundances of V, Ti, and Fe group dements, and high Al2O3/TiO2 and Ti/Th ratios. Some beds have clear negative Eu anomalies. The sources of clay rocks are interpreted as mixtures of volcanic ash and continental debris. The variation of compositions in different beds shows different mixing ratios at different times when the Sichuan basin was formed. It is suggested that the volcanic ash might come from the middle Jurassic volcanic arc in the Tethys which was about 600 km to the west.
    Geochemical Characteristics and Tectonic Setting of Zhangjiaba and Xinyuan Plutons in South Qinling
    YAN Yun-xiang, ZHANG Cheng-li
    2005, 11(3):  425-433. 
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    The Zhangjiaba and Xinyuan plutons of South Qinling were formed in the Mesozoic. They have high Al2O3, K2O contents, and are relatively enriched in LILE and poor in HFSE, with high Sr (498 × 10^-6 -623×10^-6) , low Y (5.57 × 10^-6 -24 × 10^-6) and Yb (0.52 × 10^-6 -2.13 ×10^-6) and with slightly negative or positive Eu anomalies. All these demonstrate the features of high-K calc-alkaline granitoids formed by partial melting of lower-crust materials under the thickened crust. On the other hand, needle-shaped apatite and quenched-edge texture are well developed in the enclaves in both plutons. There is a visible composition gap between enclaves and granitoids. Two different magmatic evolutional trends correspond to two different REE patterns. These evidences imply that they were resulted from mingling of two-end-member magmas derived from different sources, suggesting that there was a crust-mantle interaction in the Mesozoic and an important vertical growth of crust in Qinling area.
    Crystal Chemistry and Color Genesis of the Hemimorphite Jinding Pb-Zn Deposit, Yunnan Province
    LIU Yan1 2, DENG Jun1 2, WANG Qing-fei1 2, ZHOU Ying-hua2
    2005, 11(3):  434-441. 
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    For the purpose of understanding the spectra characteristics and color-causing mechanism of the hemimorphite found in the oxidation zones of Jinding Pb-Zn deposits, 5 techniques were applied to analyse this mineral: wet chemical analysis, IR, LRM, XRD and EMPA. The complete chemical compositions of the mineral were obtained and large emphasis was put on the possible color causing elements, such as Cu, Fe and Ni. The white and blue hemimorphite samples were tested by XRD and IR to reveal if there are other minerals intermingled with hemimorphite. At the same time, the cell parameters were calculated. The average cell parameters are a = 0. 8372nm, b = 1. 0702nm, and c =0.5116nm. The absorption bands of crystal structure in the range of infrared spectra (180 -452 cm^-1) were obtained, which were not reported before. Meanwhile, the structure, the structure water and crystal water were studied through infrared spectra. The peaks and absorption bands of infrared and Raman spectra were assigned. Generally, partial substitutions of Cu^2+ for Zn^2+ may cause the blue color of the hemimorphite. In addition, the blue and white hemimorphites share the same crystal structure based on XRD, IR and LRM. The glass luster and dust luster of the hemimophite are related with the large amount of crystal water in it.
    Pore Structure Test of Jurassic Red-Bed in Yanzhou Mining Area, Shandong Province, and Its Affecting Factors
    WU En-jiang1, HAN Bao-ping2, WANG Gui-liang2, PEN Zi-cheng1, LIU Gui-jian1
    2005, 11(3):  442-452. 
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    Jurassic continental red beds in Yanzhou mining area, Shangdong Province, contains abundant underground water, in which pore is the main water-bearing space. Combining micro-appearance observation with hydrargyrum-pressure experiments, pore types of red beds, micro-structure features and affecting factors of pore structures have been systematically studied. Main pore types of the red beds, such as interparticle soluble enlarged pore, contracted interparticle pore, gelatinous materials soluble pore, interparticle pore, and inter-crystal pore have been described in detail. Based on the data from 93 rock samples, the porosity of red bed varies from 0. 58% to 23.97% , and the average pore diameter varies from 2.3 um to 46.8 urn. Results show that different rock types have different micro-structures. The rock samples with same pore quantity may have absolutely different pore structures. The water-beating ability of the rocks can be controlled by their pore structures.
    Quantitative Analysis of X-ray Diffraction for Palygorskite within Attapulgite Clay
    XlONG Fei1 2, YIN Lin1 3, CAI Yuan-feng1 3, LI Zhen1, ZHAO Bo1, YU Xin-feng1
    2005, 11(3):  453-458. 
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    There is some difficulty in the XRD quantitative analysis of attapulgite clay in application to industry. Many previous methods about the quantitative analysis also have some problems in, choosing suitable inserted standard mineral and preparing samples. In this study, palygorskite is purified from attapulgite clay by sedimentation method. Dispersant sodium polyacrylate (PAAS) is used in the experiment so that the aggregation of palygorskite can be dispersed completely. Corundum and quartz are used to prepare a series of mixture samples with 5% interval of palygorskite in the experiment. In all samples, content of corundum is constantly 50%. The National Bureau Standards (NBS) method is employed to prepare the XRD samples. Ratios of integral intensity of palygorskite to that of corundum, labeled as Ip, 110/Icor,113, are calculated with the backgroud value subtracted. A plot is obtained by content of palygorskite as X axis and ratios of Ip, 110/Icor, 113 as Y axis. Linear equation is fitted according to the curve. Feasibility of the linear equation is proved by the study of three samples from Jiangsu, China and the existence of non-crystal materials in the clay is also proved indirectly. The equation can be used in application to the practical industry production.
    One Anticline Developing from Two Ends to the Center: Baguashan Anticline in the Western Foothill of Taiwan Orogen
    ZHANG Jin1, MA Zong-jin1, WANG Qian-ying2
    2005, 11(3):  459-468. 
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    The Baguashan anticline is located in the western thrust-and-fold zone of Taiwan orogen. As a whole, the growth of this anticline is from the north to the south. However, because the dips of the detachment fault along the Jinshui shale vary along the strike, which are smaller at two ends of anticline and larger in the central part, the strata deformed in the fold also vary along the strike obviously. All these result in the plan shape of Baguashan anti- cline whose two ends convex to the west and are wider than the central narrow part. Furthermore because of the controls of structural belts ( maybe lateral lamps) along two ends of anticline, the growth of the anticline is limited. In the early time, the anticline grew from the north to the south, and in the later time it grew from the south to the north. This process of growth can well interpret the plan shape, the characteristics of fold axis, and the mechanics of different parts of Baguashan anticline, so the development of the Baguashan anticline has its own special character.