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O-Nd-Pb Isotopic Systems in Eclogite Minerals at Jinheqiao in Dabieshan and Constraints on Their Relative Diffusivity

LI Qiu-li, LI Shu-guang, ZHENG Yong-fei, GONG Bing, HONG Ji-an   

  1. School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China
  • Received:2003-06-20 Revised:2003-06-20 Online:2003-06-20 Published:2003-06-20

Abstract: Sm—Nd isochron dating and O isotope an alysis were carried out for minerals from eclogite at Jinheqiao in Dabieshan.Garnet+omphacite Sm-Nd line gives an age of 210±3 Ma.and garnet+ rutile, 237 ± 4 Ma. Amphibole occurs as corona around omphacite, indicating significant retrograde reaction during exhumation. Correspondingly, O and Sm-Nd isotopic disequilibria were observed between omphacite and garnet,resulting in an unreasonably low Sm-Nd isochorn age of 210±3 M a.Mineral-pair O isotope thermometers yielded a temperature of 695±35℃ for a quartz-garnet pair and 460±15℃ for a quartz-rutile pair.Sm-Nd isochron defined by garnet + futile with an age of 237±4 M a records the eclogite-facies prograde metamorphic time,which is considerably higher than rutile U—Pb age of 218.2 ± 1.2 Ma from the same sample.A1l these data suggest that the rate of 0 diffusion in garnet is slower than,or close to that of Nd diffusion in garnet,wheress the rates of 0 and Pb diffusion in rutile are faster than those of Nd diffusion in rutile.0 isotope an alysis on different grains of rutile gave consistent results within an alytical uncertainty;the O isotope temperature defined by the quartz-rutile pair is in agrement with a closure temperature of 470±50℃ for Pb diffusion in futile as estimated from the futile U—Pb isochron dating . These indicate that O an d Pb isotopic homogenization was achieved among different grains of rutile in the scale of han d specimen during the eclogite-facies metamorphism ,and that the rates of 0 an d Pb diffusion in rutile are similar to each other during eclogite cooling .