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    20 September 2012, Volume 18 Issue 3
    Advances and Reviews on Coalbed Methane Reservoir Formation in China
    QIN Yong
    2012, 18(3):  405. 
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    Advances and Reviews on Coalbed Methane Reservoir Formation in China

    Evolution of Coal-derived Hydrocarbon Based on the Analysis of Fluid Inclusions
    in the Permo-Carboniferous Strata of Liulin Area in the Ordos Basin
    LI Yong, TANG DaZhen, XU Gao, LI Hai, TAO Shu
    2012, 18(3):  419. 
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    Four types of fluid inclusions occur in the coal seam roof in the Liulin area including the brine liquid hydrocarbon,
    liquid-gas hydrocarbon and gas hydrocarbon. They are mainly trapped either in the quartz overgrowth and fracture of sandstone
    or in recrystallized calcites and solution holes filled calcites of limestone. Based on the thermodynamic of fluid inclusions, the
    fluid inclusions in the Shanxi Formation were classified as types of low-temperature and low salinity and of high-temperature
    and high salinity, while those in the Taiyuan Formation were defined as types of low-temperature and composite-salinity and
    of high-temperature and high salinity fluids. Types of the fluid inclusions in the Taiyuan Formation testified the superimposed
    impact of the paralic coal-forming environment to the connectivity with surface freshwater in the later period. It was suggested
    that, according to the fluid inclusions types, micro-fluorescence and thermodynamic characters of the fluid inclusions and in
    combination with the geothermal evolution analysis, the first stage of the hydrocarbon injection in the Liulin area occurred during
    Middle to Late Triassic with relatively low amount of hydrocarbon generation. The second stage which was a major period of the
    hydrocarbon generation occurred during Early Cretaceous with prolific gas inclusions and high hydrocarbon generation intensity.

    The Upper Permian Coalbed Methane Bearing System and its Sedimentary Control  in Western Guizhou, China
    SHEN YuLin, QIN Yong, GUO YangHai, REN HaiYing, WEI ZhanHang, XIE GuoLiang
    2012, 18(3):  427. 
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    Based on the observation of drilling cores and lab analysis, it is indicated that the formation of“ unattached multiple
    superimposed coalbed-methane system” is controlled by sedimentary environment remarkably. This study demonstrates that the
    distribution of low-permeability rocks in coal-bearing strata plays a part of separating in the formation of“ unattached multiple
    superimposed coalbed-methane system”. The development of impermeable gas barrier is controlled by sedimentary environments,
    under which impermeable gas barrier of low porosity and low permeability in coal-bearing strata tends to form in the area from
    delta plain facies to delta front facies, resulting in vertical coalbed-methane bearing system becoming gradually complex. For its
    oxidized environment, delta plain area is not conducive to the formation of siderite and pyrite during the penecontemporaneous
    diagenesis and early diagenesis stages. The block performance of mudstone is relatively weakened, which is near to the maximum
    transgressive surface in the sequence, making the unattached coalbed methane bearing system connected to each other,
    constituting a relatively uniform coalbed methane bearing system. The vertical coalbed methane system is relatively simple
    in delta plain area. The impermeable gas barrier with low porosity and low permeability in the coal-bearing strata is relative
    development in the delta front where the vertical coalbed methane bearing system is more complex.

    Hydrodynamic Conditions and Their Controls of Gas in Coal-bearing Strata
    in Eastern Edge of the Ordos Basin
    2012, 18(3):  433. 
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    The Eastern edge of the Ordos basin has a wide north-south span where the regional hydrodynamic conditions are still
    unclear. Based on the data of the porosity, permeability, drilling water production, hydro-chemical and isotope composition and
    coalbed methane (CBM) concentration, the control of the hydrodynamic condition to the CBM generation and accumulation in the
    area was discussed. It was shown that the sandstone aquifers and their pores and permeability develop much well in north part of
    the basin than in its south. Limestone aquifers in the Taiyuan Formation are most developed in the Sanjiao-Jixian area, resulting
    in the higher CBM content of the Shanxi Formation than that of the Taiyuan Formation. Drilling water production and the calcium
    and magnesium ion concentrations are higher in the north than in the south, and the water mineralization is positively correlated
    to CBM content. It was indicated that the groundwater in the area is more active in the north than in the south. Hydrodynamic
    condition in the north is stronger in the Shanxi Formation than in the Taiyuan Foramtion but it is opposite in the Sanjiao-Jixian
    orea of the south. Weak run-off to stagnant groundwater in the middle and high coal-rank area located in the south of the Bode orea
    is in favor of the CBM accumulation. Active groundwater and good cap-rocks in the low and middle coal-rank area in the north of
    the Baode provide a key for the generation and accumulation of the secondary bio-gas.

    Structural and Hydrogeological Controls of Coalbed Methane Preservation
    in the Eastern Ordos Basin
    2012, 18(3):  438. 
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    Based on field investigation and data of borehole pumping test, the structure, hydrogeology and their controls to the
    coalbed methane (CBM) preservation in eastern margin of the Ordos basin were discussed. Results showed that the compression
    faults and folds with nearly south-north direction develop well in the basin margins, and the tectonic deformation weaken
    gradually towards the center of the basin, which indicates the structure both in the margin and center of the basin is all conducive
    to the CBM preservation. Five hydrological units in the area were distinguished based on the geomorphological and geological
    conditions such as the structure and groundwater recharge and discharge. Hydrodynamic in southwestern Hancheng unit is
    stronger than that in other units in the eastern, and that in the Liulin unit is strongest among the eastern units. Superposition of
    the hydrodynamic variation on the tectonic setting makes the differentiation of CBM preservation conditions. CBM content in
    middle Yellow River depression increases with the increase of the burial depth. Hydrodynamic favorable to CBM preservation in
    northern Liulin unit occurs at the western part of the Liulin Spring in the unit. Groundwater dynamic at the northern part of the
    Longmenshan unit may be favorable to CBM preservation. Good CBM preservation occurs in the northwest part of the Hancheng
    unit due to the stagnant groundwater.

    Tectonic Control of Coalbed Methane Reservoirs in Panxian, Western Guizhou
    2012, 18(3):  447. 
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    Turning towards the geological complex conditions of coalbed methane (CBM) in Panxian, western Guizhou, the tectonic
    control of the CBM reservoir was discussed taking the tectonic evolution as a basic approach and combining with the geological
    field observation and the lab analysis. Results showed that four tectonic stages in the area have be experienced including the
    intra-continental rift stage from Devonian to Permian, stable platform stage from Early to Middle Triassic, continental depression
    stage from Late Triassic to Middle Jurassic and fault-folded uplift stage form Late Jurassic to Quaternary. Coal seams occur in
    the synclines indicating an obvious syncline control of CBM resources. The Late Permian coal-bearing strata were characterized
    by two periods of subside burials, two periods of uplift erosions and three periods of coalifications. Middle Yanshanian tectonic
    movement was a key period to CBM reservoiring, in which the modern occurrence of the coal rank was built by the telemagmatic
    metamorphism on the deep burial metamorphism setting. High CBM content in the area is caused importantly by the compressive
    and compressive-shear structures. Modern tectonic stress field with the nearly east-west direction of horizontal compression might
    make the coal seam permeability in the Tucheng and Zhaozihe synclines higher than that in the Panguan and Jiupuan synclines.

    Evolution of Textures and Stress-Strain Environments of
    Tectonically-Deformed Coals
    2012, 18(3):  453. 
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    Based on X-ray Diffraction (XRD) analysis of tectonically-deformed coals with different deformation types and extent,
    the evolution of the tectonically-deformed coals and their stress-strain environments were studied. The results show that the space
    between aromatic layers(d 002) of weak-deformed coals decrease in stepfunction with the step point of about R o,max=0.69%, as the
    rank of coalification increases, and change a little following the step point; the d 002 of scaly coal Ⅱ is smallest, crumpled-mylonitic
    coal’s d 002, which is almost equal to flaky coal Ⅱ’s d 002, is between the d 002 of weak-deformed coals and scaly coal Ⅱ, and the d 002
    of crumpled coal is slightly larger than that of crumpled-mylonitic coal. The other parameter L c changes in a coordinate way with
    d 002. It is indicated that tectonically-deformed coals with various deformation types and extent are corresponding to different types
    and extent of stress-strain action, which change the macro- and microtexture of coal as well as the texture of aromatic nucleus.
    The effect of each stress-strain environment upon the aromatic nucleus of coal is different. The stress-strain environments forming
    tectonically-deformed coals can be classified into three types, i.e. brittle cataclastic, ductile, and shearing. Weak and moderate
    brittle cataclastic deformation actions have little effects on the development of aromatic nucleus of coal. Ductile and shearing
    deformation actions are featured by conditions of certain temperature and confining pressure and directional stress action,

    respectively. The former are benefit for shedding of small radicles and developing of new aromatic rings, the later are helpful to
    the ordering of molecular structure. Both of them promote the growth of aromatic nucleus in coal.

    Accumulation and Geological Controls of Low-Rank Coalbed Methane in Southeastern Junggar Basin
    2012, 18(3):  460. 
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    Coalbed methane (CBM) resources in the Junggar Basin, Xinjiang, China are abundant. The most favorable targets
    for CBM resources occur in the southern Junggar Basin, with stable and thick coal seams, shallow buried depth and higher CBM
    content. The lack of geological knowledge of CBM accumulation and generation is the reason why the exploration in the region
    had not achieved for many years. Based on the analysis of CBM accumulating conditions, it was considered that the favorable
    geological controls of CBM accumulation occur in southern Junggar with the higher coal rank, the better hydrological conditions
    and the abundant gas supply including the secondary biogenic gas and pyrolzed deep gas. CBM content is low in eastern Junggar
    because of the lower coal rank, higher groundwater mineralization and the poor CBM preservation. On the basis of the analysis
    abovementioned, it was suggested that the key geological controls of CBM accumulation in the southern Junggar are the structure,
    hydrology and cap-rock. Favorable structural positions could control the pyrolyed deep gas supply. The hydrogeological conditions
    might be favorable of secondary biogenic gas generation. The favorable cap rocks could make CBM to be preserved.

    Analysis of Geological Conditions of Deep Coalbed Methane Reservoiring in the Eastern Ordos Basin
    2012, 18(3):  465. 
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          Burial depth of the developing coalbed methane (CBM) fields in the eastern Ordos Basin is less than 1200 m. Abundant
    deep CBM resources need to be explorated and developed. For this reason, occurrence, coal-rank, CBM content and distribution
    of deep coal seams in the eastern Ordos Basin were analyzed. It was suggested that the regional distribution pattern of the gasbearing
    characteristics and permeability of depth coal seams might be further complicated due to the overlay of two westward
    protruding shallow zone to overall depth pattern of the Upper Paleozoic. It was found that the regional coal-rank occurrence of
    the Late Paleozoic coal seams is similar to that of coal seam depth, which indicates a major control of deep burial metamorphism
    to the coal rank setting. Occurrence of deep CBM content was predicted. It was suggested that the content might decrease with
    the increase of the depth once the burial depth of coal seam exceeds a critical depth. Two types of coal-derived gas reservoir
    models were set up including self-generation plus self-storage, endogenous generation plus exogenetic storage. It was suggested
    that the paragenesis of both adsorption CBM and free coal-derived gas reservoirs provides a viable resource for the gas combined
    development.

    Generation and Evolution of Hrdrocarbon Gases From Coal in the Presence of Molybdenum
    2012, 18(3):  474. 
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    Behavior and evolution of the hydrocarbon generation from the organic matter in coal under the occurrence of
    molybdenum is poorly understood. Thus, a set of the catalytic simulation for the gas generation of the coal sample with addition
    of elemental molybdenum was carried out with the gold tube autoclave. It was found that the peaks of total and monomeric
    hydrocarbon gas generation occurred whether or not to add molybdenum, which indicates that there is still large potential for
    methane generation in very high maturity stage with simulated vitrinite reflectance (SVR) greater than 4.0 percent. Added
    molybdenum had a weak suppression on the gas hydrocarbon generation from the coal when the SVR was less than 3.0 percent.
    The promotion to a certuin extent occur after the SVR is more than 3.0 percent. Interrelationship of the methane yields between
    the raw and molybdenum-added coal samples was similar to that of total gaseous hydrocarbon yield, the ethane yield of the
    molybdenum-added sample was higher than that of the raw sample coal once the SVR exceeds to 3.0 percent, and the propane
    to pentane yields under the occurrence of molybdenum were slightly higher than or approximately equal to those from the raw
    samples after their generation peaks. It was suggested that the added molybdenum was not involved in the early to medium staqes
    of the hydrocarbon generation through a thermal degradation, but played a promoting effect on late thermal cracking hydrocarbon

    generation, possibly resulting from the differences of the catalytic reaction space during various maturation stages of coal

    Origin of Coalbed Methane in Baode, Northeastern Ordos Basin
    2012, 18(3):  479. 
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    Trial coalbed methane (CBM) production of the well group in Baode has achieved a relatively satisfactory result but the
    CBM genesis is still unconfirmed. Based on the data of the components and stable isotope composition of the CBM sampled from
    the producing wells, the genesis was discussed. Results showed that the CBM is mainly composed of the methane with little heavy
    hydrocarbons. Carbon isotopic composition of the methane is obviously light, and partial data of the carbon and hydrogen isotopes
    of the methane plot within the transitional range between the thermogenic and biogenic gases. Carbon isotopic composition of the
    carbon dioxide of the samples is relatively heavy and is negatively correlated to the carbon isotopic composition of the methane. It
    was suggested that the coalbed methane in the area has a mixed thermogenic and biogenic origin, but thermogenic gas is the main
    with composition minor of biogenic gas. Biogenic methane was formed through the reduction of carbon dioxide. The chemistry
    and hydrodynamics of the coalbed water and the porosity and permeability of the strata in the area were favorable of the active
    population of the methanogenic bacteria.

    Processes and Possible Pathways of Biogenic Coalbed Methane Generation From Lignites Based on Parent Methanogen
    2012, 18(3):  485. 
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    Using the parent anaerobic methanogen flora enriched from lignites in the Zhaotong basin, Yunnan, a simulation
    experiment was carried out in order to analyze the process and possible approach of the biogenic coalbed gas (CBG) generation.
    Results showed that the process of the biogenic CBG generation in a period of 130 days underwent at least two gas generation
    peaks with the higher gas generation rate at the first peak than that at the secondary peak. Gas produced during the first peak
    came mainly from the huminite group and the biodegradation of the inertinite and liptinite groups was strengthened relatively
    during the secondary peak. Plots of the carbon isotopic composition to the hydrogen isotopic composition of the simulated methane
    indicated a major approach of the acetate fermentation by which the biogenic methane was generated. During the stimulation
    process, the methane concentration raised with the drop of the carbon dioxide concentration. Carbon isotopic composition of the
    methane tended to become lighter and the hydrogen isotope composition to become heavier in the late period of the simulation
    process. These data indicate the carbon dioxide-reduction of the partial methane generated in the late period of the stimulation.

    Desorption and its Geological Controls of Coalbed Methane in Hancheng Demonstration Area
    2012, 18(3):  490. 
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    Desorptivity of coalbed methane (CBM) is one of the key controls to CBM recovery ratio and production. Based on the
    canister desorption experiments and relevant data of the 62 coal core samples from the Hancheng block, the correlation of the
    desorptivity to the geological controls such as the coal rank, coal quality and maceral composition is discussed. Results showed
    that the desorption ratios of all samples are higher than 80%, commonly from 90% to 95%. Adsorption time ranges from 0.03d
    to 10d, in which the desorption ratios of the 82% samples are less than 6d. CBM desorbed with the stages, the reduction of the
    desorption rate was resulted from the change of the average CBM content. Initial desorption rate and its attenuation are related
    to the pore texture and connectivity in the samples. Desorption ratio has not a clear correlation with the coal rank but reduces
    obviously with the increase of ash yield. Moreover, desorption ratio increases with increasing the vitrinite content and reduces with
    decreasing the inertinite content. Adsorption time shortens discretely with the increase of the fixed carbon or moisture contents,
    but has not a obvious correlation with the ash yield and maceral content.

    Discussion on Abnomal Heavy Hydrocabon Concentration based on Natural Desorption Process of Coal Samples From the Enhong Syncline, Yunnan
    2012, 18(3):  495. 
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    Heavy hydrocarbon gas (HHG) in the coal seam of the Enhong syncline is extremely high in concentration but the gas
    source is still unclear. Samples of the gas naturally desorbed from the Enhong’s coal sample was intensively collected and tested
    in order to discuss the origin of the abnormal HHG. It was shown that the fractionation of the desorbed gas components is obvious
    during the desorption. As the desorption time extends, the HHG concentration becomes obviously higher, the carbon isotope of
    the methane becomes heavier. The carbon isotopic composition of the alkane always presents a positive carbon isotope series,
    but the carbon isotopic composition of the HHG did not change significantly. Gas component concentration is related well to the
    carbon isotopic composition but the opposite trend occurs for the methane and HHG. It was suggested that the CBM in the Enhong
    syncline originated mainly from the thermogenic gas of the organic matter in coal but the possibility that the part of the methane is
    secondary biogenic can not be excluded.

    Methane Adsorption Response of Stepwise-Solvent-Extracted Vitrains and Possible Driving Mechanism
    2012, 18(3):  500. 
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    Five sets of vitrain samples were extracted in stepwith organic solvents such as carbon disulfide, benzene, acetone
    and tetrahydrofuran. The isothermal methane adsorptivity of the raw and extracted samples was measured, and the dynamics of
    the adsorption differences among extracted samples were analyzed. It was found that the step extraction changes the adsorptivity
    but the change direction and magnitude depends on the coalification degree, in which the second coalification jump plays a key
    role on the adsorption change. It was suggested that the change may be originated in two major mechanisms, i.e., the physical
    expansion and chemical shrinkage of adsorption space. Carbon disulfide extraction produces a physical expansion effect to
    flame, gas and early coking coals but a chemical shrinkage effect to late coking coal and anthracite. Damage of the benzene and
    tetrahydrofuran extractions to the adsorptivity is mainly resulted from chemical shrinkage and the effect of acetone extraction is
    mainly expressed as the physical expansion.