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大别山碧溪岭榴辉岩的K—Ca同位素定年多硅白云母含过剩氩的新证据

彭子成1 2, 王俊新1, 李曙光1, 刘桂建1, 朱术云1, 张 巽1   

  1. 1. 中国科学技术大学地球和空间科学学院,合肥 230026; 2. 中国科学院 地球环境研究所 黄土与第四纪地质国家重点实验室, 西安 710054
  • 收稿日期:2002-12-20 修回日期:2002-12-20 出版日期:2002-12-20 发布日期:2002-12-20

he K-Ca Age of the Eclogite from Bixiling,Dabie M ountains:A New Evidence of the Excess Argon in Phengite

PENG Zi-cheng1 2, WANG Jun-xin1, LI Shu-guang1, LIU Gui-jian1, ZHU Xue-yun1, ZHANG Xun1   

  1. 1. The School of Earth and Space Science, University of Science and Technology of China, Hefei 230026, China; 2. State Key laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710054, China
  • Received:2002-12-20 Revised:2002-12-20 Online:2002-12-20 Published:2002-12-20

摘要: ^40K可以进行分支衰变成^40Ar和^40Ca。在正常情况下,这时^40K-^40Ar或^31Ar-40^Ar年龄与^40K-^40Ca年龄在误差范围内应该一臻,测定了国家钾标样的含量,国家钾长石(W03116)和球团矿(W7200)的钾钙含量,国内K-Ar法标准矿物黑云母(ZBH-25)和角闪石(ZBJ)的钾钙含量以及Tachiti标样的(^40Ca/^42Ca)比值和含量。结果实测值与标称值在误差范围内一致,对大别山碧溪岭超高压变质榴辉岩的多硅白云母,绿辉石和石榴子石进行了(^40Ca/^42Ca)和(^40K/^42Ca)的测定。由15组数据构成的等时线斜率S=0.1208±0.0423,相应的K-Ca年龄为228±75Ma,然而多硅白云母和绿辉石的^39Ar-^40Ar等时线年龄分别为807.1±32.6Ma和456.7±27.2Ma,在误差范围内明显地高于^40K-^40Ca等时线年龄,这给出了前者存在过剩氩的直接证据,此外,K-Ca等时线的初始值(^40Ca/^42Ca)i为151.424±0.013,相应的ζCa为±27。由于地幔岩的ζCa≈0,所以前者表明榴辉岩的原岩具有典型的大陆地壳性质,这为大别山超高压变质岩体是由大陆物质俯冲至上地幔的深度,然后折返至大陆的形成过程提出了又一个判据。

Abstract: 40K is subjected to branched decay to form 40Ar by electron capture and 40Ca by beta (β-)decay.In general cases,the 40K-40Ar or 39Ar-40Ar and 40K-40Ca ages are consistent in the error range.In order to test the measuring system ,the K and Ca contents and their isotopic compositions in the potassium feldspar(W03116),pellet(W7200),biotite(ZBH-25),hornblende(ZBJ) national standards,and the Tachiti secondary international standard have been determined and their results are certified values in the error range.The 40K-40Ca isochron was made for 30 data of 40Ca/42Ca and 40K/42Ca in phengite, omphacite and garnet in eclogite from Bixiling,Dabie Mountains and showed a slope of S=0.1208±0.0423.corresponding to a 40K-40Ca age of 228±75Ma. This is close to the Rb-Sr age of 212 M a and Sm-Nd age of 239Ma in the eror range.However.the 39Ar-40Ar isochron ages of phengite and omphacite are 807.1± 32.6 Ma and 456.7± 27.2 Ma, respectively,which are obviously older than that of 40K-40Ca age.It provides a direct evidence for phengite and omphacite with excess argon due to both isotopic systems of K-Ar an d K -Ca belonging to the branched decays. In addition.the primary value(40 Ca/40Ca)i of the K-Ca isochron is equal to 151.424±0.013.and corresponds to Ca +27.Because the mantle rocks have Ca=0,it is certified that the original rocks of the eclogite have the continental character. This provides a new criterion that the ultrahigh-pressure metamorphic rocks at Bixiling in Dabie Mountains were formed during the process of subduction of the continental materials to the upper mantle and their exhumation back to the continent.