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白云鄂博碳酸盐矿物的矿物化学成分标型特征

杨学明 杨晓勇 张培善 M.J.Le Bas R.N.wilson   

  1. 中国科学技术大学地球与空间科学系
  • 收稿日期:1998-03-20 修回日期:1998-03-20 出版日期:1998-03-20 发布日期:1998-03-20

TYPOM ORPHIC CHARACTERISTICS OF CARBONATE MINERALS FROM BAYAN OBO, INNER MONGOLIA, CHINA

Yang Xue-ming1;2, Yang Xiao-yong1;2, Zhang Pei-shan3, M. J. Le Bas4, R. N. Wilson4   

  1. 1.Department of Earth and space Sciences, University Science and Technology of China, Hefei 230026; 2. The Advanced Centre for Earth Science and Astronomy, Third World Academy Science, USYC, Hefei; 3. Institute of Geology of Chinese Academy of Sciences, Beijing 100029; 4. Department of Geology, University of Leicester, Leicester LE1 7RH, U.K.
  • Received:1998-03-20 Revised:1998-03-20 Online:1998-03-20 Published:1998-03-20

摘要: 对白云鄂博地区不同产状的碳酸盐矿物进行了系统的电子探针分析,其结果表明白云鄂博REE-Nb-Fe矿床的赋矿白云岩中,无论是粗粒结构的,还是细粒结构的白云岩,其主要造岩矿物白云石或者铁白云石均具高锰(MnO〉0.5wt%)和高锶(SrO〉1.5wt%)的特征,与矿床北东方向0 ̄3.5km范围内切割五台群花岗片麻岩-混合岩及白云鄂博群碎屑岩的火成碳酸岩岩墙中的碳酸盐矿物非常相似。它们完全不同于宽沟段裂以北典型沉积石灰岩厦白云质石灰岩中的方解石和白云(MnO<0.1wt% ,SrO<0.1wt% )。赋矿白云岩中自云石的锶和锰含量系统变他反映碳酸岩浆发生了分离结晶作用,其结果可以导致其余岩浆中REE高度富集.本文认为碳酸盐矿物的锶和锰含量可以作为识别其成囡的重要标型特征,其氧化物MnO>0.15wt% 和Sr>0.15wt%为火成碳酸岩的标志。

Abstract: Carbonate rocks from Bayan Obo, Inner Mongolia, can be divided into sedimentary limestone and dolostone (H8a), coarse-grained dolomite marble(H8c) fine-grained dolomite marble(H8f)and carbonatite dykes(D)based on their textures and occurrences. H8, which shows very weak metamorphism and deformation is distributed to the north of the Kuangou fault zone, occurring together with quartz sandstone, sandstone and shale to form the Bayan Obo Group of middle Proterzoic age of normal sedimentary origin. In contrast to H8a, however, H8c and H8f are distributed to the south of the Kuangou fault zone and have distinctive petrologicl features, both of which are strongly deformed and sheared and metamorphosed to dolomite marble. H8 which hosts ores is mainly consisted of dolomite, apatite, magnetite, and pyroclore etc. These minerals show strong lineation which is the result of numerous clusters of euhedral magnetite and apatite drawn out into granular schlieren. The lineation resulted from shearing stretching and deformation is interpreted to be related to the regional thrusting and folding H8, is close to the ores and is composed of dolomite, magnetite, monazite, bastnaesite and parisite etc. The fine-grained monazites are lined to fil1 fractures in dolomites. Similar to H8c, the minerals in H8f also show strong lineation. Electronic microprobe is used to analyze the chemica1 compositions of carbonate minerals from these rocks at Bayan Obo. Results show that the main rock-forming minerals-dolomite or ankerite in ore-hosted rock from giant Bayan Obo REE-Nb-Fe ore deposit are similar to those from carbonatite dykes(D), which occur 0 to 3.5 km northeast to the Bayan Obo deposit, and cut the Archean granitic gneiss and migmatite of the Wutai Group and the Proterozoic detrita1 rocks of the Bayan Obo Group. A1l these minerals contain MnO higher than 0.50 wt% and SrO greater than 0.15wt, which are identical to the typical signatures of the mantle derived carbonatite elsewhere in the world. However, they differ completely in chemica1 compositions from calcite and dolomite, with MnO and SrO content 1ess than 0.1 wt%, in typical sedimentary 1imestone and dolostone (H8a) north to the Kuangou fault. The variation of MnO and SrO content in dolomite from ore-hosted dolomite can be interpreted by fractional crystallization of a carhonatltic magma origining from the mantle, which results in REE enrichment in the evolved residual magma. MnO and SrO content in carbonate minerals can be used as an important typomorphic characteristics to identify the genesis of minerals. It is suggested that the value of MnO and SrO content in carbonate minerals higher than 0.15 wt% is an indicator of crbonatite from sedimentary carbonate rocks.