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矿物氧扩散与氧同位素退化交换作用

傅斌 汪学军 郑永飞   

  1. 中国科学技术大学地球与空间科学系
  • 收稿日期:1995-03-20 修回日期:1995-03-20 出版日期:1995-09-20 发布日期:1995-09-20

OXYGEN DIFFUSION IN MINERALS AND ITS BEARING ON RETROGRADE ISOTOPE EXCHANGE IN ROCKS

Fu Bin1;2, Wang Xue-jun1, Zheng Yong-fei1;2,   

  1. 1. Department of Earth and Space Sciences, University of Science and Technology of China, Heifei 230026; 2. Advanced Centre for Earth Science and Astronomy, Third Word Academy of Science, Heifei 230026
  • Received:1995-03-20 Revised:1995-03-20 Online:1995-09-20 Published:1995-09-20

摘要: 本文从理论上解论上解析了同位素封闭体系内的矿物氧扩散性质,火成岩从冷却为质岩从高峰变质温度冷却过程中的所发生的扩散作用会层致矿物晶体内部及晶粒间的氧同位素重新分配,两种不同的矿物氧扩散-同位素交换模式都可以用来模拟这种性质。实例研究进一步阐明了扩散对氧同位素组成的影响。

Abstract: Effects of oxygen self-diffusion in minerals on oxygen isotope composition have been studied theoretically. When igneous or metamorphic rocks slowly cool under closed system conditions, oxygen isotope redistribution can occur due to diffusion-controlled retrograde isotope theoretically calculated oxygen isotope fractionation factors, the oxygen isotope compositions of some case examples have been estimated for given cooling rates. During cooling of metamorphic and plutonic rocks, oxygen diffusion between minerals can be the principal mechanism to cause retrograde isotope exchange. There are two types of models to simulate the effects of oxygen diffusion: (1) Giletti model, a simple cooling rate model which predicts the effect of slow cooling in a closed-system on the oxygen isotope composition of single minerals; (2) Eiler model, a fast grain boundary model which predicts both the zonation profile of δ18O within mineral grains and the bulkδ18O value of each mineral in the rock. Both models have advantages and disadvantages with respect to reality. However, application of the models will help to interpret possible variations in oxygen isotope composition of minerals and to preclude effects of open-system exchange (e.g., water/rock interaction, magma degassing). Case examples are tested to show the applicability of the diffusion models to natural assemblages. These include the granulite-grade metamorphic rock from Einasleigh in Australia, the tonalite from San Jose in USA and the granite from Suzhou in East China. The theoretical prediction forδ18O agrees well with the experimentally measured values. For the Suzhou granite, the lowδ18O value is interpreted to indicate the interaction of its protolith with meteoric water at high temperatures. The water/rock interaction after granite emplacement can be excluded by the constraints from diffusion-controlled oxygen isotope exchange.