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J4 ›› 2011, Vol. 17 ›› Issue (1): 39-45.

• 微生物—矿物相互作用专栏 • 上一篇    下一篇

微生物所协同的天然金红石日光催化作用研究

李  艳,鲁安怀   

  1. 造山带与地壳演化教育部重点实验室,北京大学 地球与空间科学学院
  • 收稿日期:2010-01-07 修回日期:2011-02-18 出版日期:2011-03-20 发布日期:2011-03-20
  • 通讯作者: 鲁安怀,教授,博士生导师,主要从事环境矿物学教学和研究;
  • 作者简介:李艳,1982年生,女,讲师,研究方向:环境矿物学;E-mail: liyan-pku@pku.edu.cn
  • 基金资助:

      国家重点基础研究发展计划资助项目(973项目)(2007CB815602)

Natural rutile-involved photocatalytic process assisted by microorganism

LI Yan, LU An-huai    

  1. The Key Laboratory of Orogenic Belts and Crustal Evolution, School of Earth and Space Sciences, Peking University, Beijing 100871,  China
  • Received:2010-01-07 Revised:2011-02-18 Online:2011-03-20 Published:2011-03-20
  • Contact: Lu Anhuai, Professor.

摘要:

本文揭示了自然界中可能存在的一种新的矿物和微生物交互作用形式,即微生物通过生物电化学作用参与到半导体
矿物的日光催化作用过程中。模拟日光光源下“产电”微生物与天然半导体矿物金红石交互实验结果显示,金红石的光催
化作用促进了矿物端元的反应速率,提高了电子在微生物和矿物之间的转移效率,使微生物电子传递链末端电子能量得到
提升。二者协同作用可提高微生物或半导体矿物单独作用时对污染物如Cr(Ⅵ)的还原处理效果。该研究为环境污染治理提
供了一种矿物与微生物协同作用新理念。

关键词: 半导体矿物, 太阳能, 矿物-微生物交互作用, 光催化

Abstract:

A novel  interactive manner between minerals and microorganisms was proposed  in  this study,  i.e. microorganisms
participate in the semiconducting mineral photocatalytic process via a bioelectrochemical reaction. The experimental results showed
that in the interactive system including simulated sunlight, “electricigens” and natural rutile, the photocatalysis of natural rutile
improved  the cathodic reaction kinetics, promoted  the electron  transfer efficiency and elevated  the electron energy of  the end of
the microbial electron transfer chain. The synergistic interaction between microorganism and semiconducting minerals enhanced
the  reduction efficiency of pollutants such as Cr(Ⅵ). The proposed  interactive pathway would be expected as an alternative
effective technology for future wastewater treatment.

Key words: semiconducting mineral, solar energy, mineral-micoorganism interaction, photocatalysis

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