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• 矿床 岩石 地球化学 • 上一篇    下一篇

江西朱溪超大型钨矿床成矿年代学、矿物学及成矿过程研究

于全,陈国华,康川   

  • 出版日期:2018-12-20 发布日期:2019-01-15

Study of Metallogenic Chronology, Mineralogy and Ore-Forming Process of the Superlarge Tungsten Deposits in Zhuxi, Jiangxi Province

YU Quan,CHEN Guohua,KANG Chuan   

  • Online:2018-12-20 Published:2019-01-15

摘要: :位于江南造山带东部的江西朱溪钨矿,是近年发现的一个超大型钨矿床,其矿体主要由矽卡岩型白钨矿组成,产于
燕山期侵入岩与碳酸盐岩接触带的矽卡岩或矽卡岩化大理岩中。为了更好地认识朱溪钨矿的特征和成因,文章采集了花岗
岩和矽卡岩的钻孔样品,进行了岩石学、矿物学、岩石地球化学和同位素年代学的分析。研究表明,朱溪矿区的黑云母花
岗岩具有高硅、富碱、高分异的特征,属于钙碱性、过铝质花岗岩,微量元素中Rb,U,Ta等元素富集,Ba,Nb,Sr和Ti
等元素亏损。稀土元素总量偏低,轻稀土相对富集。矽卡岩矿物的电子探针成分结果表明,其中石榴子石主要为钙铝榴
石-钙铁榴石端元组分;单斜辉石以透辉石-钙铁辉石系列为主。与白钨矿密切共生的矽卡岩矿物中,萤石、符山石、磷灰
石和榍石等富氟的矿物大量出现,表明朱溪钨矿成矿流体为富氟体系,这有利于钨的运移和沉淀。白钨矿REE配分曲线及
Mo含量变化所反映的流体性质表明,朱溪钨矿在矽卡岩阶段,总的矿化环境则由氧化向还原环境变化。利用朱溪含矿矽卡
岩中榍石进行了原位LA-ICP-MS U-Pb定年,206Pb/238U加权平均年龄为153±2 Ma,结果显示朱溪钨矿的成矿时代为晚侏罗
世,属燕山期岩浆活动后的产物。

关键词: 朱溪钨矿, 矽卡岩, 白钨矿, 榍石U-Pb定年

Abstract: The Zhuxi tungsten deposits are superlarge ore deposits, discovered in recent years in the eastern segment of Jiangnan
orogenic belt. The ore bodies of the Zhuxi deposits mainly occur in the skarn and skarnized marble at the contact zone between
Yanshan intrusive rocks and carbonate. To better understand the characteristics and genesis of Zhuxi tungsten deposits, we collected
both granites and skarns samples, and carried out research on petrology, mineralogy, geochemistry and chronology. The petrological
and geochemical characteristics of the biotite granites are calc-alkaline and peraluminous,enriched in Rb,U,Ta,and depleted in
Ba,Nb,Sr and Ti. The rare earth elements are characterized by the relatively low total content with a slightly rightly-dipping REE
pattern. Electron microprobe analyses reveal that the garnet is mainly composed of grossularite-andradite, and the pyroxene mainly
belongs to diopside-andradite series. Sheelite coexists with many F-rich minerals such as fluorite, apatite, titantites, and vesuvianite.
The F-enriched ore-forming fluid facilitates the transfer of W and the mineralization of scheelite in the Zhuxi deposits. The fluid
characteristic reflected by the REE distribution curve and Mo content variations of scheelite indicate that the mineralization
environment of zhuxi tungsten deposits changed from oxidation to reduction environment in the skarn stage. In-situ U-Pb dating of
titanite by LA-ICP-MS shows that titanite from the skarn sample yields a weighted mean 206Pb /238U age of 153±2 Ma. The main
mineralization event occured in the Yanshanian, which is consistent with the age of Zhuxi granites .

Key words: Zhuxi tungsten deposits, skarn, scheelite, titantite U-Pb daing