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    20 December 2011, Volume 17 Issue 4
    Identification and Genesis of the Early Cretaceous Shoshonitic Volcanic Rock Series in Central Jiangxi Province
    WU Jun-qi, TAN Gui-li, ZHANG Bang-tong, LING Hong-fei, CHEN Pei-rong 
    2011, 17(4):  479-491. 
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    The forth unit of the Daguding Group in central Jiangxi Province consists of intermediate to basic volcanic rocks in the
    Shengyuan basin and adjacent areas. Our systematic study of petrology and geochemistry of this unit identifies that these rocks belong to typical interplate shoshonitic volcanic rock series, which are characterized by high contents of total alkali and K2O, low contents of TiO2 and iron, and an enrichment of the LREE and LILE elements. The Rb-Sr isochron age of the shoshonite series is (138±8.8)Ma, with distinctively high initial Sr isotopic ratios; intermediate initial Nd isotopic ratios and enriched radiogenic Pb. In addition,the shoshonite series shows a remarkable Dupal anomaly (△7/4Pb=14~19.6 with an average value of 16; △8/4Pb=70.5~97 withan average value of 89.2; △Sr=121.5~161.8 with an average value of 136.3). The correlations of Sr-Nd, Sr-Pb, Nd-Pb and Pb-Pbisotopes imply a mixing source of the depleted mantle (DM) endmember and the lithosphere enriched mantle (LEM) endmember.According to the two-component (Sr-Nd) mixing equation, the source of the shoshonite series is composed of about 37% DM

    Geochemical Characteristics of the Late Mesozoic Basalts in Southeastern Zhejiang Province and Constraints on Magma Source Materials
    CUI Yu-rong, XIE Zhi, WANG Bin, CHEN Jiang-feng, YU Yun-wen, HE Jian-feng 
    2011, 17(4):  492-512. 
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    The late Mesozoic basalts occur in the southeastern Zhejiang Province together with acidic volcanic rocks, which can be divided into upper and lower rock series (URS and LRS). Major, trace elements and Sr-Nd-Pb isotopic features of these basalts are studied in this paper to provide insights into the nature of their magma sources and evolution processes. Both the
    URS and LRS basalts are enriched in alkaline and Al elements. However, their characteristics of trace elements are different.
    The samples from Tiantai and Qingtian of LRS are enriched in LREEs, Ba, Pb and Sr, and depleted in Nb, Ta, Zr and Hf with Eu
    negative anomalies. The basalts from Yongjiahuatan, Ningboxuantandi, Xinchangjingling and Yongjiajingjiashan basalts of URS
    show similar trace elements and REEs natures to those of the samples from LRS, but basalts from Wuyi of URS show no negative Ta, Nb anomalies, while the trace element features of the basalts from Jinqu Basin are on the average. Correspondingly, isotopic compositions of these basalts are also variable apparently. The initial isotopic ratios of basalts from LRS range are as follows: ISr= 0.70850~ 0.70897, εNd(t )=-5.6~-4.1, (206Pb/204Pb)i =18.21~18.38, (207Pb/204Pb)i =15.55~15.58, (208Pb/204Pb)i =38.26~38.49,which are approximate to those of the intermediate-acid magmatic rocks in LRS, indicating that their magmatic sources were contaminated significantly by the lower crustal materials. Basalts from URS demonstrate a marked difference from those of the LRS in isotopic features by showing similar groups as the characteristics of trace elements. The samples from Yongjiahuatan,Ningboxuantandi, Xinchangjingling and Yongjiajingjiashan of URS have enriched Sr-Nd isotopic compositions with I Sr=0.70734~0.70936, εNd(t )=-7.1~-2.1, (206Pb/204Pb)i =18.01~18.40, (207Pb/204Pb)i =15.54~15.62, (208Pb/204Pb)i = 37.99~38.62,suggesting that these basalts are most likely generated from active continental margin. The samples from Wuyi and Jinqu Basins have the characteristics similar to OIB with I Sr = 0.70533~0.70589, εNd(t ) = 0.4~3.3, (206Pb/204Pb)i = 17.23~18.11, (207Pb/204Pb)i=15.46~15.53, (208Pb/204Pb)i = 36.91~38.43, towards the end member of depleted mantle. Based on elements and isotopic compositions of the Late Mesozoic basalts from the southeastern Zhejiang Province, the sources of the basalt are significantlydifferent and varied obviously with time. It could be concluded that the initial magma of basalts of LRS may be derived fromthe ancient lithospheric mantle, subducted altered oceanic crust and contaminated by lower crustal materials. The source of the basalts of URS may contain the materials of the lithospheric mantle which is similar to basalts from LRS, depleted OIB-like mantle and lower crust materials. It is also concluded the formation of the late Mesozoic basalts in the southeastern Zhejiang Province may be related to the Pacific plate subduction, but the influence of delamination of the lithospheric mantle could not be ruled out.Since that, much further information of petrology and/or mantle xenoliths is needed for the specific discussion about the dynamic process.

    The Confirmation of Yanshanian Biotite Granite in the Hehuaping Sn-Pb-Zn District, Southern Hunan Province, China
    ZHANG Rong-qing, LU Jian-jun, WANG Ru-cheng, YAO Yuan, ZHU Jin-chu, MA Dong-shen
    2011, 17(4):  513-520. 
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    The Wangxianling granite was emplaced at the Indosinian (Triassic) period. The previous research considered that the
    Hehuaping Sn-Pb-Zn deposit was an Indosinian deposit related to the Wangxianling pluton. Based on many years of investigationin the field and study of rocks from drilling holes, a buried pluton with lithological characteristics different from the Wangxianling granite was discovered in the Hehuaping district. A zircon U-Pb age of (157.1±0.8) Ma for the coarse-grained biotite granite from drilling hole was obtained by La-MC-ICP-MS, which suggests an early Yanshanian (Jurassic) emplacement. This granite is characterised by A/CNK value of 1.02, total REE content of 357×10-6, LREE/HREE ratio of 2.83 and Zr+Nb+Ce+Y content of398×10-6, on average. These features are similar to those of A-type granite and markedly different from those of the WangxianlingS-type granite. This Yanshanian granite, named as Hehuaping granite, has an affinity of the tin-bearing granites in the Nanling Range. Therefore, we argue that the Hehuaping Sn-Pb-Zn deposit is related to the Yanshanian buried Hehuaping pluton.

    Research on the Location Prediction of Gold Deposit in Altay of Xinjiang With the Entropy-Weighted Method
    ZHANG Ming-chao, SHEN Wei, CUI Jing, CHEN Hui, LIU Xiang-chong
    2011, 17(4):  521-530. 
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    This paper combines entropy and gray correlation degrees to study the relationship between geological variables and
    ore units to locate ore targets. The 87 key geological variables are obtained from geological, geochemical and geophysical data.
    Based on the theories and methods of metallogenic prognosis by using synthetic information, the study area (in Altay, Xinjiang)
    is divided to 16 gold deposit concentrated areas and 14 gold anomaly-concentrated areas. Then, this article introduces entropyweighted
    method to deal with qualitative and quantitative variables, respectively, and then use the gray correlation to describe
    the similarities between the deposit units. The results show that gravitational gradient, aeromagnetic, and catchment are effective
    indicators to look for gold mines and unit number 6, 22, 18, 19 and so on contain a large gold deposit, respectively, which was
    confirmed by other means. This shows that the method can be effectively applied to delineate and assess ore-finding targets.

    Chloritization of Qitianling Granite Related to Bailashui Tin Deposit,Southern Hunan Province
    ZHAO Zhan-jie, LU Jian-jun, YAO Yuan, ZHANG Rong-qing, GUO Wei-min, ZHANG Huai-f
    2011, 17(4):  531-545. 
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    The Bailashui tin deposit is located in Qitianling Yanshanian biotite granite, Southern Hunan province. Chloritization
    is a universal hydrothermal alteration in this ore-bearing granite. Based on the research of the samples collected from the
    drillhole, we found a notable variation in the chloritized degree of the granite. This study was carried out by selecting three groups
    of granite samples which displayed notable different degree of chloritization. The chloritization nhich closely related to oreforming
    in the Sn-bearing granite had been discussed. The results indicated that, in the granite samples of different degrees of
    chloritization the petrography and chemical composition of chlorite changed with a series of obviously variable characteristics.
    According to the analysis of micropetrography and relevant geochemical data, some conclusions could be drew as follows. Themetasomatic sequence of rock-forming minerals in the granite replaced by chlorite is: amphibole and biotite→plagioclase and
    potassium feldspar→quartz. The variable shape of chlorite was, on the one hand, related to the composition of chlorite; on the
    other hand, related to the crystal texture of rock-forming minerals which were replaced by chlorite. As the chloritization of granite
    was stronger, the LOI and Zn content of whole-rock samples would be higher, and the Cl contents losing to hydrothermal liquid
    from original rock would be more. With the chloritized degree of granite becoming stronger, main compositions of chlorites would
    present regular variations. The Si content of chlorite decreased in the process of chloritization. Al elements were released after
    the breakdown and dissolution of feldspar. The mobilization and redistribution of Al on the thin-section scale increased the
    aluminum content of chlorite. Fe element were brought in to the chrorite by hydrotherm. The amounts of chlorite formed depended
    on how much Fe had been introduced into the hydrothermal system. The Mg for the formation of chlorite was primarily related to
    the redistribution of Mg which was released from mafic minerals. Mn element was mainly brought in to the chlorite by the outer
    hydrotherm.

     

    Laboratory Inversion for Wall Solute Fluxes from Breakthrough Curves
    LI Guang-quan, GAO Yang, ZHAO Bei
    2011, 17(4):  546-551. 
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    Spring breakthrough curves provide a convenient and effective way to investigate migration and fate of contaminants
    in karst aquifers. During a dry season, contaminants sequestered inside limestone are released through the wall into conduits, mix
    with conduit water, and are then transported to the downstream springs. Thus breakthrough curves acquired at the springs may
    be inverted to obtain the fluxes of solutes across the conduit wall as sequestered contaminants are released. Using the analytical
    solution based upon an advection-dilution model, we invert for the wall solute fluxes from 40 breakthrough curves measured in
    the laboratory. The basic shape of the fluxes is similar to that of the breakthrough curves. The inhomogeneity of water flux across
    the wall is evident on the breakthrough curves, and appears as very strong oscillations on the wall solute fluxes. Therefore, it is
    concluded that wall solute flux has higher resolution to the inhomogeneity of water flux across the wall than spring breakthrough
    curve does. The wall solute fluxes are an intermediate quantity connecting spring breakthrough curves with earlier distribution of
    contaminants in limestone. This study provides a new approach to investigate the release of contaminants across the conduit wall.

    Fractal Analysis of Spatial Distribution of Faults around West Lake and
    its Influence on the Distribution of Karst Collapse
    SHEN Chao, PAN Mao, ZHAO Zeng-yu, LIANG He
    2011, 17(4):  552-561. 
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    In this paper, we studied fractal characteristics of the spatial distribution of faults around West Lake with the gridcoverage
    method based on Fractal theory, and then we analyzed the karst collapse susceptibility in this area. First, we outlined
    briefly the geological background, the analytical methods, and calculated the fractal dimensions of both the NE-trending faults
    and NW-trending faults. The results show that the fractal dimension can reflect the spatial characteristics of the fault distribution;
    Second, by the study of the karst collapse of the zone, we discussed the relationship between the fractal dimensions and the
    distribution of karst collapse. The results show that the NE-trending faults and NW-trending faults complement each other
    in spatial distribution, and the distribution of karst collapse positively correlated with the fractal dimensions. In addition, we
    quantitatively analyzed how faults control the distribution of karst collapse, which is vital for local engineering construction.

    An Application of Phase-Weighted Stacks to Study the Crustal Structures
    in the Southeastern Margin of the Ordos Block
    LU Yi-feng, XU Ming-jie, WANG Liang-shu, MI Ning, LI Hua, YU Da-yong
    2011, 17(4):  562-568. 
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    In order to study the crustal structures in the southeastern margin of the Ordos Block, a portable broadband
    seismograph array with 22 stations was deployed in the study area. Instead of the linear stacking, a non-linear stacking techniquenamed the phase-weighted stack (PWS) was used to stack the radial receiver functions for each station. The results show that thedepth of Moho in the study area gradually decreases towards the southeast. The Moho discontinuity in different parts of the study area exhibits different features: the depth of Moho in the Ordos block is between 42 and 38 km; the Moho in Weihe-Shanxi graben bulges up by about 3 km; In the Xionger-Funiu Mountains, the depth of Moho is betweem 35 and 33 km; the Moho in the Hehuai basin appears to be complex. To conclude, the PWS Method is useful to enhance the S/N (signal/noise) ratio and determine the depth of Moho beneath the stations in the study area.

    Detecting Crustal and Upper Mantle Structures of the Eastern Margin of the Ordos Using Receiver Functions
    HUANG Tao, MI Ning, WANG Liang-shu, XU Ming-jie, LI Hua, YU Da-yong
    2011, 17(4):  569-576. 
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           A data set of 1876 three-component, P wave seismograms from 22 stations deployed at Ordos and Taihang mountains
    was collected to investigate crust and upper mantle structure of that area. By using the array deconvolution method, the vertical,
    radial, and tangential receiver functions of all events are obtained. All radial receiver functions are then migrated to produce a
    seismic image. The image shows that from Ordos to Bohai Bay basin, the crust becomes thinner from about 52 km to 37 km, and the Moho generally dips to the west at a small angle. In central part of Ordos basin, the crust is thickest, reaching 52 km; at the eastern edge of Ordos, the thickness decreases to 43 km. From Taihang Mountain to Bohai Bay basin, the thickness of the crust changes from 45 km to 37 km. Under the Shanxi Graben, the Moho suddenly uplifts by approximately 8-10 km in comparison to that of both sides, and the rise of the Moho and the depression of the surface show a mirror-image relationship.

    Reservior Structures of the Upper Ordovician Reef Complexes in Tazhong 83-16 Well Area, Tarim Block
    WANG Zhen-yu, ZHANG Yun-feng, YANG Hong-qiang, SU Dong-po, ZHANG Li-juan, DENG X
    2011, 17(4):  577-585. 
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    Carbonate sequences of the upper Ordovician Lianglitag Formation along the Tazhong 83-Tazhong 16 well blocks,
    Slope Break I,Tarim Block is 170-300 m thick and notable as reservoirs of oil-gas.This suite of sedimentary facies from the
    platform margin is generally shown as overlapping of reef complexes with 4-5 cycles. Lithological facies as well as enhanced karst and tectonic action onward are considerable factors controlling the trap formation.Based on the analysis of drilling cores, thin sections and logging parameters, types of reservoir space are recognized as cave,intragranularly dissolved pores,intercrystalline dissolved pores,moldic pore,biologic dorsal pore,organic framework pore and micro-fracture.The features of the void structures as well as their associations are catalogued as vug,fracture-vug, and fracture configuration types, respectively,and are in similar abundance. Nevertheless, the perspective of reservoirs with good conditions of porosity and permeability are favorable for spatial distribution from the platform margin of the Slope-break I. Such a model is subtly consistent with reef-bank complexes. Outer setting of the platform margin has ideal lithologiolal facies that experienced multiple reformation phases and show weak filling.The reservoir pattern shows that fracture-vug and vug types are dominant. Therefore, we consider it a potential area for highquality type I andⅡ reservoirs. However, inner setting of the platform margin along the Tazhong 12-Tazhong 16 well blocks is dominated by fractures and high lithological filling during later periods that resulted in type Ⅱ and Ⅲreservoir.

    Sedimentary Organic Facies of the Palaeogene Upper E2-3s4 Source Rocks in Jiyang Depression
    LIU Qing, ZHANG Lin-ye, SONG Guo-qi, WANG Ru 
    2011, 17(4):  586-593. 
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    Investigation of sedimentary structures,palaeontology associations and organic matter occurrence shows that the lacustrine deposition of Palaeogene upper E2-3s4 hydrocarbon source rocks is significantly controlled by the bottom anoxicity in
    Jiyang Depression. Based on the previous studies on sedimentary organic facies and palaeo-oxygen facies,the source rocks are divided into four types of sedimentary organic facies including anoxic facies anaerobic facies,dysaerobic facies, and aerobic
    facies,and the identification markers of each facies are summarized. Together with well logging data,the upper E2-3s4 source rocks are evaluated by single well,well-tie and distribution of sedimentary organic facies analyses. The results show great difference in the occurrence of the upper E2-3s4 hydrocarbon source rocks from the east to the west,and the upper source rocks in the east are obviously superior to those in the west. In addition,it is found that the distribution of excellent source rocks is mainly controlled by the northwest and northeast faulting movement. The finding will have great significance for making future exploration strategy and understanding deep subtle reservoir formation.

    Effects of Oil Emplacement on Diagenetic Evolution of Sandstone Reservoir in Yanchang Formation, Southeastern Ordos Basin
    YUAN Zhen, LI Wen-hou, GUO Yan-qin
    2011, 17(4):  594-604. 
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    Using comprehensive lithological, mineralogical, and geochemical methods, this paper studies the diagenetic
    interaction system after oil injection into the sandstone reservoir of Triassic Yanchang formation in southeastern Ordos basin. Wedemonstrate that the change of diagenetic environment after oil emplacement in certain degree affected the diagenetic evolution of the reservoir. In the arkose reservoir of this area, organic acid and carbon dioxide appeared in a large amount after oil injection and the pH value decreased, which promoted dissolution as the rock matrix of feldspar particles, resulted in the development of secondary pores, and enhanced the property of reservoir. However, due to low oil saturation, the change of diagenetic environment restrained illite growth slightly. To certain extent, the pore“ bridging” cement of illite reduced the property of reservoir.Meanwhile, the oil emplacement resulted in dissolution of carbonate cement formed in the early diagenetic stage. While the diagenetic temperature was higher than 100℃, the thermal evolution of organic matter would produce higher carbon dioxide partial pressure, which buffered pH value, precipitated a large amount of iron carbonate cements, and compacted the reservoir sediments.

    Research on Macro Features and Micro-mechanism of Deep Coal Soft Rocks Degradation in Water
    QIAN Zi-wei, JIANG Zhen-quan, SUN Qiang, ZHU Shu-yun, LI Dong-lin
    2011, 17(4):  605-610. 
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    With the development of deep coal resources, research on the water stability of soft rocks containing coals becomes
    very important. In Juye Coal field, the roof rocks and floor soft rocks, mainly consists of mudstone at 900-1200m below surface,
    is typical soft rocks for deep coal. The macro features and micro cale degradation mechanism of deep coal soft rocks in water in
    Juye Coal Field have been analyzed by water stability experiment, X-ray diffraction and scanning electron microscopy. The result
    shows that the water stability of soft rocks is poor, and soft rocks startet to disintegrate in 30 minutes after being soaked. The
    clay minerals of the rock samples, mainly kaolinite and illite/montmorillonite interstratified, show significantly osteoporotic and
    alignment in structure. The degradation of deep coal soft rocks is due to the expansion of clay minerals inside and outside through the analysis, and the main factor that leads to poor water stability of rock samples is the structural features of soft rocks.

    Chemical Weathering Characteristics and Controlling Factors of the Ili Loess, Xinjiang
    LI Chuan-xiang, SONG You-gui
    2011, 17(4):  611-619. 
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    The element distribution characteristics and chemical weathering intensity of the loess and paleosol at the Zhaosu
    section in the Ili Basin are preliminarily studied through element geochemical analysis. Through comparing with the type
    Luochuan loess-palesol section of the Quaternary aeolian deposit in the Loess Plateau, we draw the following conclusions. The
    contents of major elements in the loess and paleosol at the Zhaosu section in the Ili region show similar variations,which indicate that both of them experienced the similar degree of chemical weathering after deposition. Major elements have the same changing trend as that of the Loess Plateau, with enriched CaO and MgO and depleted Na2O and P2O5. CIA index, Na/K ratio and A-CN-K diagrams all indicate that the Ili loess and paleosol experienced weaker chemical weathering than that in the Loess Plateau. Furthermore, there is no obvious chemical weathering differentiation between loess and paleosol. The climate conditions such as hydro-thermal combination (precipitation, temperature and evaporation, etc.) may play an important role in chemical weathering of loess and paleosol in the Ili basin.

    The Formation Mechanism and Coastal Evolution of Tangdao Bay, Qingdao, Eastern China
    LUO Qin-min, QIN Yong-peng, JIA Zhen-zhen
    2011, 17(4):  620-627. 
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    Integrated with field observations and analysis of fault structures this study investigated the formation mechanism and
    coastal evolution of Tangdao Bay in Qingdao, eastern China. The result indicates that three elements are essential for the formation of Tangdao Bay (1) NNE-NE trending faults coutrolled the structural framework and extendsional direction; (2) Quaternary glacial erosion casted a profile that is charaterized by lowlands in the middle and high terrains on both sides; (3) Around 10 ka BP, as a large-scale transgression occurred, sea water flooded the lowlands and Tangdao Bay was formed. After the transgression, Tangdao Bay has experienced three geological evolution stages since Holocene, while sea level changes, waves and tides are dominating factors for coastal changes, respectively. With the connection of a tombolo between Liujiadao and Shilingzi in Song Dynasty, Tangdao Bay evolved into a semi-enclosed bay. By the Qing Dynasty, the coastal landforms became similar to what they are today