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我国稀土铌钽矿物学研究回顾与展望

张培善, 陶克捷, 杨主明   

  1. 中国科学院 地质研究所, 北京 100029
  • 收稿日期:2000-06-20 修回日期:2000-06-20 出版日期:2000-06-20 发布日期:2000-06-20

RE-Nb-Ta Mineralogical Investigations in China

ZHANG Pei-shan, TAO Ke-jie, YANG Zhu-ming   

  1. Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
  • Received:2000-06-20 Revised:2000-06-20 Online:2000-06-20 Published:2000-06-20

摘要: 作为高新技术原料用的稀土铌钽是国家发展的支柱之一, 稀土铌钽矿物学研究在与国家的技术进步同步前进。 通过研究,已经获得了我国产出的全部百余种稀土铌钽矿物的化学组成、物理性质、稀土配 分、结晶参数、共生组合和产状成因的全面系统的鉴定描述成果;发现了多种稀土铌钽新物,并提出许多新规律和新理论,建立了易解石和褐钇铌矿两个新的矿物族;确定了稀土铌钽铁锰钨的复杂氧化物的晶体结构关系;确立变生矿物学为矿物学研究的一个特殊分支,探讨了稀土次生富集的离子型稀土矿成矿机理。

Abstract: Up to the present day more than one hundred RE-Nb-Ta mine ral species are known in China. Most of their properties, such as chemical compo sitions, physical and optical properties, X-ray diffraction data, occurrences a nd mineral associations, have been described in detail. Majority of these min erals are widespread and a few of them are less common or very rare. These phenomena reveal the special geological conditions and metallogeneses of RE, Nb -Ta in China. The main scientific achievements on RE, Nb-Ta mineralogy in Chin a are summarized as follows: Considerable amount of new mineral species of RE, Nb -Ta have been discovered, s uch as huanghoite, cebaite and zhonghuacerite of fluorocarbonates, ashanite, qit i anlingite and changbaiite of oxides, fergusonite-(Ce), fergusonite-(Nd), f ergu sonite-beta-(Ce), and fergusonite-beta-(Nd) of tantalo-niobates, aeschynite -(Nd), nioboaeschynite-(Ce) and nioboaeschynite-(Nd) of meta-titano-tantalo-niobat es, m onazite-(Nd) of phosphates, daqingshanite of phosphates-carbonates, hingganite , baotit e and saimaite of silicates. The morphotropic series of rare earths-alkaline ea rths-fluoro-carbonate minerals have been discovered and established. The isomorphous series of Na-Ca-Sr-RE fluorocarbonate minerals was also disc ove red, and the regularities of isovalent and heterovalent cation isomorphism was p roved. Through a detailed investigation of meta-RE-Ti-niobate minerals the re gu larity of double isomorphism was established and proved. Two mineral groups, aes chy nite and fergusonite, have been established and developed. The concentration reg ularity of odd number light RE in the Bayun Obo Deposit was discovered. The c rystal structure relationship between complex oxide minerals of Nb, Ta, Fe, Mn a nd W, such as columbite-tantalite, ixiolite, wolframoixiolite, wodginite and qi t ianlingite were clarified. Based on a detailed study of the metamict minerals th e metamict mineralogy has been established as a branch of mineralogy. The regula rity of secondary enrichment of rare earth in the weathering surface of granite bodies has been found. The RE-Nb-Ta ore deposits of ion type and their metallo genic model have been worked out. The Chinese geologists and mineralogists have much to do in RE, Nb and Ta minera logy and they will gain important achievements in the future.