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黄土中蜗牛壳Mn^2+的EPR研究及其古气候意义

盛雪芬1, 陈骏1, 季峻峰1, 眭云霞2   

  1. 1. 南京大学地球科学系表生地球化学研究所和成矿作用国家重点实验室,江苏南京210093; 2.南京大学现代分析中心,江苏南京210093
  • 收稿日期:2002-03-20 修回日期:2002-03-20 出版日期:2002-03-20 发布日期:2002-03-20

An EPR Study on Mollusk Shells from Loess-Paleosol Sequences in the Loess Plateau,Central China

SHENG Xue-fen1, CHEN dun1, JI Jun-feng1, SUI Yun-xia2   

  1. 1. Institute of Surficial Geochemistry, Deparment of Earth Sciences, and State Key Laboratory of Mineral Deposits Research, Nanjing University, Nanjing 210093, China; 2. Center of Material Analysis, Nanjing University, Nanjing 210093, China
  • Received:2002-03-20 Revised:2002-03-20 Online:2002-03-20 Published:2002-03-20

摘要: 对黄土高原陕西省洛川和甘肃省西峰剖面中黄土-古土壤层中的蜗牛壳进行了EPR波谱分析,同时对洛川地区的现代蜗牛壳也进行了测定。结果显示:(1)不同种类的蜗牛壳具有相近的EPR信号强度,表明不同种类的蜗牛对Mn^2+的吸收没有差异性。(2)黄土层中蜗牛壳的EPR信号强度远大于占土壤中的,即黄土中蜗牛壳所含的Mn^2+远大于古土壤中的蜗牛壳的Mn^2+的含量,说明前者生活在比较还原的条件下,后者形成环境的氧化性较高。因此本认为为蜗牛壳中Mn^2+的含量可反映其生长环境中Mn^2+的含量和氧化还原条件,对古气候的重建具有重要意义。

Abstract: Electron paramagnetic resonmnce(EPR)spectrum won induced to decipher the paleoclimatic change information in the mollusk shells from the Luoe huan and Xifeng sections in the Loess Plateau.centra1 China The EPR analysis results showed the presence of trace amount of Mn2+ in the mollusk shells carbohate and no obvious tribal discrepancy of the EPR spectrum in tensities among different species of modern mollusks. The EPR intensities of the mollusk shells from the loess are significantly different from those in the paleosols The EPR signals of Mn2+ in the mollusk shells from the loess, which were formed under cold oonditions, are stronger than those from the paleosols which were developed under warmer conditions.Therefore,the Mn2+ content in the mollusk shells from the loess is higher than that from the paleosols It is concluded that during the glacial period, mollusks lived in more reducing environment.0n the contrary, during the interglacial period.the environment won more oxidizing. Thus the content of Mn2+ in the mollusk shells reflects the redox oonditions of the environment. The EPR signals of Mn2+ in the mollusk shells from loess and paleosols provide a new approach to reveal important information of environment changes.