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济阳坳陷高青—平南断裂带CO2气藏中稀有气体地球化学特征

申宝剑1,2 ,秦建中2,胡文瑄1,黄智龙3,王 杰2   

  1. 1. 南京大学 地球科学系, 南京 210093;2. 中国石化石油勘探开发研究院 无锡石油地质研究所,无锡 214151;3. 中国科学院 地球化学研究所 矿床地球化学国家重点实验室,贵阳 550002
  • 收稿日期:2009-12-20 修回日期:2009-12-20 出版日期:2009-12-20 发布日期:2009-12-20

Noble Gas Geochemistry of CO2 Gas Pool in Gaoqing-Pingnan Fault Zone,Jiyang Depression

SHEN Bao-jian1,2, QIN Jian-zhong2, HU Wen-xuan1, HUANG Zhi-long3, WANG Jie2   

  1. 1. Department of Earth Sciences, Nanjing University, Nanjing 210093, China 2. Wuxi Research Institute of Oil Geology, SINOPEC, Wuxi 214151, China 3. State Key Laboratory of Ore Deposits Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China
  • Received:2009-12-20 Revised:2009-12-20 Online:2009-12-20 Published:2009-12-20

摘要: 济阳坳陷高青—平南发育多个CO2气藏,对气藏组分、同位素以及组分同位素相关组合进行分析,认为气藏中CO2主要是幔源-岩浆成因。气藏同时具有高40Ar/36Ar和高3He/4He值表明:气藏中稀有气体主要来自幔源,同时有部分壳源混入;气藏中4He/40Ar*平均值为2.15,说明该地区气藏形成主要以岩浆缓慢脱气为主,大规模CO2及稀有气体是岩浆冷却结晶阶段所释放。其形成机理为:在随岩浆上升的过程中,随着压力和温度不断下降以及岩浆成分的变化,岩浆中CO2及稀有气体溶解度也随之降低并析出,产生的大量CO2及稀有气体沿着深大断裂及一些二、三级断裂交汇处输送至地层的各类圈闭中,并在适当的位置聚集成藏。

Abstract: In the surroundings of the Gaoqing-Pingnan fault zone five CO2 gas reservoirs are developed. Based on the data on compositions, isotope geochemistry and CO2/3He of the reservoirs, it is shown that CO2 distributed in the Gaoqing area was mostly originated from the mantle-sourced inorganic material associated with magmatic rocks. The 3He/4He ratios range in 2.02×10-6~8.34×10-6 and 40Ar/36Ar ratios range in 628.9~3178. The higher 3He/4He and 40Ar/36Ar ratios in CO2 gas pools prove a major mantle-magmatic origin of the noble gases, with a part of crustal source gas mixed. The average 4He/40Ar* of 2.15 shows a slow degassing rate of magma. Its formation mechanism can be interpreted as follows: During the magma rising, the pressure and te perature would decrease, the magma composition would change, and the solubility of CO2 and noble gases in magma would also decrease. Consequently, the CO2 and noble gases could be separated from the magma, and large amount of CO2 and rare gases could be transported to the various stratigraphic traps along the deep faults and some second- and third-order faults.