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    20 December 2015, Volume 21 Issue 4
    ThePhaseTransitionofPyriteThermalDecomposition inNitrogenGas
    SHI Yadan, CHEN Tianhu, LI Ping, ZHU Xiao, YANG Yan
    2015, 21(4):  577. 
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     The phase transition of pyrite to monoclinic pyrrhotite and monoclinic pyrrhotite to hexagonal pyrrhotite in the nitrogen atmosphere has been investigated. The study was performed using differential thermal analysis and thermo-gravimetric analyzer (DTA-TGA), X-ray powder diffractometer (XRD) and magnetic susceptibility meter. The decomposition of pyrite begins at the temperature of about 400℃. At the temperature below 500℃, there is no phase change. As temperature increases to 500-600℃, pyrite phase begins to transform to monoclinic pyrrhotite and the transformation rate rises as the temperature rises. And the magnetic susceptibility is also higher as a result of the existence of monoclinic pyrrhotite. The rate of pyrite transformation to monoclinic pyrrhotite is higher than the rate of monoclinic pyrrhotite transformation to hexagonal pyrrhotite. With the temperature elevating, the two rates increase as well. When the temperature is higher than 600℃, hexagonal pyrrhotite, even troilite (FeS), is the primary product. The rate of pyrite transformation to monoclinic pyrrhotite is lower than the rate of monoclinic pyrrhotite transformation to hexagonal pyrrhotite.

    TheComparativeStudiesonCa2+/Sr2+ BiomineralizationInducdedby DifferentMicrobes
    HUANG Ting, LIU Mingxue*, DONG Faqin, LIU Yuanyuan, GUO Yuting
    2015, 21(4):  584. 
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    The Deinococcus radiodurans, Saccharomyces cerevisiae and Escherichia coli were selected as organic substrate for simulatingbiomineralizationofcarbonatetostudythemodulationeffectsforcalciumandstrontiumbiomineralization.Thecrystal morphology,phaseandgrainsizewereanalyzedwithSEM,FT-IRandXRD.Theresultsshowedthat:(1)when[Ca2+]/[Sr2+]=2,amixture ofaragoniteandcolumnarcalcitecrystalswasformedwithouttheadditionofmicrobe,butthespindle-shapedcalcitecrystalwasformed inthemicrobialgroup.Atpresent,3kindsofmicrobeswereabletoinducestrontiumionsintothecalciumcarbonatecrystal;(2)when [Ca2+]/[Sr2+]=1,thesparsespindle-shapedaragonitecrystalswereformedintheabsenceofbacteria.Theclosespindle-shapedand aragoniteclustercrystalswereformedintheadditionof Saccharomyces cerevisiae or Escherichia coli.Theycanpartlyinhibitthe strontiumionsintothecalciumcarbonatecrystal.Whilethecrystalswerecauliflower-likecalciteinDeinococcus radioduransgroup,it stillcaninducethestrontiumionstodisplacecalciumions;(3)when[Ca2+]/[Sr2+]=0.5,aragoniteaggregatewithirregularsizewas formedintheabsenceofbacteria.Thespindle-shapedoraragoniteclustercrystalswereformedinthemicrobialsystem,theycanpartly

    inhibitthestrontiumionsintothecalciumcarbonatecrystal.Theresultssuggestedthatthehighconcentrationofcalciumionsmaybe favorabletocalcitephase,whilehighconcentrationofstrontiumionstoaragonitephase.

    MolecularDynamicsSimulationoftheWettability ofKaoliniteAndIllite
    XUE Rong,DENG Qian,LU Xiancai*,ZHANG Lihu,ZHANG Yingchun
    2015, 21(4):  594. 
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    :Claymineralsarewidelydistributedinsoilsandsedimentaryrocks.Thesurfacewettabilityofclaymineraliscloselyrelated toprimarypetroleummigrationinargillaceoussourcerocks,andmobilityoforganicpollutantinsoils.Aimingatinvestigatingthe influencesofsurfacewettabilityofclaymineralsontheprimarymigrationofhydrocarbon,thisstudyconstructsslitporeswithwallsof kaoliniteandillitebasalsurface.Thespatialdistributionofwaterandorganicmattersintheporesystemshasbeenrevealedusing moleculardynamicssimulations.Thedifferenceinwettabilityofclaymineralinpurewaterandinsalinewaterhasbeendisclosed. Differentbehaviorsofhydrocarbon,alcohol,andbenzenehavealsobeenrevealed.Itisindicatedthatthebasalsurfaceofillitealways presentshydrophilicaswellsiloxanesurfaceofkaoliniteishydrophobicandhydroxylsurfacehydrophilic.ThepresenceofNaClalters hydrophobicsiloxanesurfaceintototallyhydrophilic.Inaddition,theorganicmatterwithpolargroupstendstobeadsorbedonto hydrophilicclaysurfacealthoughthesemoleculesaggregatetogetherintheporewater,whichleadstotheirdifferentdistribution.

    TheNewFormationWaysofSphericalCarbonateMinerals InducedbyBacteria:ExampleofCitrobactersp.StrainGW-M
    GUO Wenwen, LI Fuchun*, MA Heng, XU Qinglong
    2015, 21(4):  603. 
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     Inordertounderstandtheformationmechanismofcarbonatemineralsinducedbymicrobes,cultureexperimentswitha durationof165dayswereperformedunderthemediationofstrainGW-Misolatedfromsoil.MineralspeciesweredeterminedbyX-ray diffraction,andthemorphologiesofprecipitatedcarbonateswereobservedusingscanningelectronmicroscopy.Theresultsshowedthat the carbonate minerals (calcite and monohydrocalcite) induced by strain GW-M featured various morphologies, mainly spherical morphology.Incontrast,morphologiesofcarbonatemineralsformedintheasepticexperimentswererelativelysimple.Threeways mightleadtotheformationofsphericalmineralsundertheactionofstrainGW-M.(1)Thefirstwaywassingledumbbell-shaped mineralswithfinecrystalsgatheredfasteronbothendsthanthemiddlepartofthedumbbell,changingdumbbell-shapedmineralsinto sphericalones.(2)Thesecondwaywastwocrosseddumbbell-shapedmineralswithfinecrystalsgatheredfasteronbothendsthanthe middlepartofthetwodumbbells,resultinginsphericalminerals.(3)Thefinalwaywasthreecrosseddumbbell-shapedmineralswith finecrystalsgatheredfasteronbothendsthanthemiddlepartofthethreedumbbells,eventuallyevolvingintosphericalminerals.

    StudyontheRemovalofPb2+ byBiomineralizationMedia viaMicroalgae
    HAN Ran, LIN Wenting, YANG Peng, HUANG Zhen, LIU Minghua, CHENG Yangjian*
    2015, 21(4):  608. 
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    As the contributor to the primary productivity, alga plays an important role in biogeochemical cycles through bioaccumulationandbiomineralizationofheavymetals.Inthispaper,westudiedtheremovalandmineralizationofPb2+ usingthe microalgae.TheresultsshowthatthemicroalgaehadastrongremovalcapacityforPb2+anditwasafastprocess.Withtheincreasing concentrationofPb2+,theremovalofPb2+alsoincreases.Intheconditionofweakacid(pH=5.0),theremovalofPb2+wasbetter.The removalamountwas423.2×10-3withtheinitialPb2+concentrationof100mg/L,pH5.0,andthecontacttimeof40min.AtomicForce Microscope(AFM)resultsshowedthattheshapeandsizeofthecellhadbeenchangedaftertheinteractionwithPb2+ andthecell surfacebecamerough.FourierTransformInfrared(FT-IR)revealedthatcellsurfacefunctionalgroups,suchascarboxyl,amido,and phosphonates,wereinvolvedintheremovalofPb2+.X-raydiffraction(XRD)patternshowsthat,undertheeffectofmicroalgae,leadions weremineralizedasPb5(PO4)3OH.

    PerformanceandMechanismsfortheRemovalofCopperIonsfrom AqueousSolutionsbyClayeyDolomite
    QIU Gao, XIE Qiaoqin, CHEN Tianhu*, LIU Haibo, XIE Jingjing, LI Hongwei, TIAN Yi
    2015, 21(4):  616. 
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     In comparison to common dolomite and palygorskite clay, the effects of parameters such as pH, contact time, initial concentrationofcopperonremovalofcopperionsusingclayeydolomiteinpalygorskiteclaydepositwasinvestigatedusingstatic adsorptionexperiments.Thekineticsofcopperremovalwasdiscussedbythepseudo-first-order,thepseudo-second-orderandthe Elovichmodel,andthesorptionisothermwasanalyzedbyLangmuirandFreundlichisothermequations.Theresultsshowthatthe effectofpHontheremovalofcopper(II)ionbyclayeydolomitewaslessthantheothertwo.Morethan85%ofcopper(II)ionswere removedinthepHrangeof3to5andtheoptimumpHis5.Thekineticdataoftheremovalofcopperbyclayeydolomitefittedthe pseudo-second-orderkineticmodelverywell.Theremovalrateaswellastheefficiencywasthehighest.Theisothermdatacanbe described by the Freundlich model and the removal capacity was 186.2×10-3. The removal mechanisms were mainly surface precipitationinducedbythemineral-waterinteractionsandelectrostaticattractionbetweenpalygorskiteandthenewlyformedcolloid [Cu2CO3(OH)2].Thepresentstudyconcludesthatclayeydolomiteismoreeffectivebecauseoftheintergrowthofnanoscalepalygorskite andsub-micronporousdolomite,leadingtothehigh-efficientremovalofcopperionsthanthecommondolomiteandpalygorskiteclay, anditpossessesthepotentialfortreatingcopperwastewater.

    StudyofInternal-tideDepositsandItsExistingProblems
    HE Youbin, HUANG Wei
    2015, 21(4):  623. 
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    Studyofinternal-tidedepositsisarelativelynewresearchfieldindeep-watersedimentology.Sincethefirstexampleof internal-tidedepositswasidentifiedin1990,sedimentologistshavemadegreatefforts,discoveredaseriesofexamplesofinternal-tide deposits,summarizeddepositionalcharacteristics,sedimentarysuccessions,anddepositionalmodelofinternal-tidedepositsidentified. Internal-tidedepositsareconsideredasapotentialreservoirofoilandgas.Butsofar,theexamplesofinternal-tidedepositsidentified are very limited. A series of problems in the study of internal-tide deposits remain to be solved. First, the existing criteria for identificationandrecognitionofinternal-tidedepositsarenotperfect.Second,thetypicalexamplesofmoderninternal-tidedepositsare verylimited.Soitisdifficulttofullyunderstandtheimpactofinternaltidesonsedimentation.Third,relevantresearchresultsof marinephysicshavenotbeenappliedintostudyofinternal-tidedeposits,relatedsimulationexperimentsofinternal-tidedepositshave notbeencarriedoutandthedepositionalcharacteristicsofinternal-tidesexistinginancientstratahavenotbeenusedtoinvestigatethe physicalcharacteristicsofinternaltides,whicharecriticaltostudytheformationprocess,formationmechanism,formationcondition, andformationenvironmentofinternal-tidedeposits.Finally,understandingofthesignificanceofinternal-tidedepositsisnotenough.In futureresearch,relevantresearchresultsofmarinephysicsshouldbecombinedtoobserveandstudymoderninternal-tidedeposits,and
    relatedsimulationexperimentsofinternal-tidedepositsshouldbecarriedout.Inaddition,inversionresearchofancientinternal-tidal depositsalsoshouldbecarriedout.Furthermore,theoreticalstudiesshouldbecombinedwiththeoilandgasresourcesinorderto betterpromotethedevelopmentofinternal-tidedepositsresearch.

    TheDiageneticImpactonReservoir-qualityEvolutionofthe CretaceousSandstonesoftheHonghaoershuteDepression
    PANRong,ZHUXiaomin,ZHANGMingjun,WANGXingxing,ZHANGJianfeng,ZANGXiaohua
    2015, 21(4):  634. 
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    Cretaceoussandstonesarecharacterizedbytheheterogeneity,thedifferentporosityevolutionprocessofdifferentdeposition settingandthedifficultyofthereservoirpredictioninHonghaoershuteDepression.Basedonthestudyofdepositionalcharacteristicsof theCretaceoussandstones,variousmethods,suchascorethinsection,castthinsectionandcoreobservation,areusedtosystematically studythediagenesisanditsinfluencesontheporosityevolutionprocess.Thereservoirs-qualityevolutionisstronglyinfluencedbythe burialhistoryanddiageneticeventsintheCretaceousofthemiddlesub-sagoftheHonghaoershuteDepression.Burialcompactionis themainfactorcausingthelossofporosityforthesandstones.Thecementsalsohaveaneffectonreducingthereservoirqualityofthe sandstones.Theacidicliquidrelatedtothehydrocarbon-expulsionoftheAershanFormationsourcerocksduringmesodiagenesis,have resultedindissolutionofthedetritalgrainsandcontributedabetterretentionofreservoirqualitytothesandstones.Thesandstonesof

    thebraideddeltaarecharacterizedbyfinegrainsize,wellsortedandlowmatrixcontents.Theporefluidmaybeflowingintothepore spacesoftherock,whichleadstotheformationofsecondaryporosity.Thinchloritefilmarounddetritalgrainspreventedpartofquartz overgrowth,whichresultedinapartofprimaryporepreservationinthesandstonesoftheslumpturbiditefan.Attentionshouldbepaid to both the negative effects of compaction and cementation on the reservoirs and the positive effects of secondary porosity and pore-liningchloritecementindifferentsedimentarybackgrounds.

    ReservoirCharacteristicsandMainControlFactorsofthe FeixianguanFormationintheQilixia-YunanchangArea, EasternSichuanBasin
    LI Rong, HU Zhonggui*, HU Mingyi, MENG Lingtao, LIU Dongxi, LIAO Yisha, PU Junwe
    2015, 21(4):  642. 
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    TheexplorationofmarinecarbonateoilandgashasgreatprospectsintheLowerTriassicFeixianguanFormation,eastof Sichuan basin. It has into entered the stratigraphic-lithologic gas pool exploration stage. Therefore, it is especially important to strengthentheresearchonthereservoircharacteristicanddistributionpredictionforthestudingarea.Basedoncoreobservationand thin section analysis, combined with the SEM, physical property and pore structure analysis, this paper analyses the reservoir developmentcharacteristicandmaincontrolfactorsandpredictsthepotentialreservoirdistributionarea.Themainreservoirrocktypes oftheFeixianguanFormationaredolomitesandooliticlimestones.Theporosityandpermeabilityarelow.Theintragranularand
    intergranularboreholearethemainreservoirspace.Thetypeofreservoirisfracture-pore.Thedevelopmentofreservoiriscontrolledby rocktypes,sedimentaryfaciesdistribution,sealevel,anddolomitization.Ooliticbeltisthefavorablereservoirfacies.Therelative regressionofthesea-levelisgoodforformingporesinthereservoir.Theburiedquartz-fine-graineddolomite,ooliticdolomitereservoir arethemostcommondiagenesisoftheFeixianguanFormation,anditisthekeytotheformationofthehighqualityreservoir.Basedon ourdataofreservoircharacteristicsandmaincontrollingfactorsoftheFeixianguanFormation,wehaveforecastedthefavorable reservoirinthestudiedarea.

    DiscussionOnDepositionalModelsofFanDeltasinSteepSlopeBelt oftheRiftBasinundertheGuidanceofSource-to-SinkSystem Theory:ACaseStudyfromtheFulaSub-basin,MugladBasin,Sudan
    WU Dong, ZHU Xiaomin*, LIU Changni, LI Yutong
    2015, 21(4):  653. 
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     Thecoarse-graineddelta,developedinsteepslopebeltofariftbasin,usuallyplaysanimportantroleinoilandgas exploration.Basedontheanalysisofcore,loggingandseismicdata,twotypesoffandeltasarerecognizedinsteepslopebeltinthe FulaSub-basin,MugladBasin,Sudan.Thetaper-shapedfandeltainJakeAreaiscomposedofrelativelycoarse-grainedsandstoneand conglomeratewithmorethicknessandwidedistribution.Thesortingandgroundingarepoorinthistypeoffandeltadeposition.Onthe contrary,thegrainismuchfinerintheplatyfandeltainKeyiAreawhilethesortingandgroundingarerelativelygood.Thesandbody isthinandlimitedspread.ThesourceissufficientinJakeAreabutinsufficientinKeyiAreaduringtheEarlyCretaceous.Thispaper bringsthetheoryofsource-to-sinksystemintothefandeltaresearch.Throughthestudyaboutclasticsupplying,transportingand accumulating,theexplanationofthesetwotypesoffandeltasaregiven,andthedepositionalmodelsarebuilt.Onlyberegardedasa whole,thesource-to-sinksystemstudycanbeutilizedtopredictthefandeltadepositioninsteepslopebeltoftheriftbasin.

    DistributionandOriginAnalysisofAnomalouslyHighPorosity ZonesoftheBayingebiFormationintheCretaceousintheChaganSag
    WEI Weihu, ZHU Xiaomin*, TAN Mingxuan, GUO Dianbin, SU Hui, JIANG Feihu
    2015, 21(4):  664. 
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    :Inordertoidentifytheformationanddistributionofhigh-qualityreservoirunderconditionsoftightsandstonereservoirs,the distributionsandoriginsoftheanomalouslyhighporosityzonesoftheBayingebiFormationintheCretaceousintheChaganSagwere studiedbyusingthedataofmeasuredporosity,loggingporosity,thinsections,blueepoxyresin-impregnatedthinsectionsandSEM. Theresultsshowthattherearetwoanomalouslyhighporosityzonesatdepthsof1900-2300mand2500-3100m,respectively,withan averageporosityrangeof7%to5.2%.Thefirstanomalouslyhighporosityzoneismainlydistributedinthemiddle-shallowhorizons, andconsistsoffinesandstoneandconglomeratereservoirsthatweredepositedinthefandeltafrontoftheCentraltectoniczone.The secondoneisdistributedinthedeephorizons,andconsistsoffinesandstonereservoirsinthefandeltafrontofWulijitectoniczoneandEhensubsag.Theoriginofanomalouslyhighporosityzonevariesindifferenttectoniczones.Theoriginofhighporosityzoneisrelated totheleachingofmeteoricwaterinCentraltectoniczone,geothermalfluiddissolutioninWulijitectoniczone,andorganicacid dissolutionintheEhensubsag.

    CharacteristicsoftheLateTriassicDeep-waterSlopeBreakBeltin SouthwesternOrdosBasinandItsControlonSandbodies
    LIU Fen,ZHU Xiaomin*,LI Yang,XU Liming,ZHU Shifa,XUE Mengge
    2015, 21(4):  674. 
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    DuringtheLateTriassic,theslopebreakbeltofdepressionlakebasinwasdevelopedintheOrdosBasin.Basedontherock types,faciesassociations,andseismicreflectioncharacters,thedeep-waterslopebreakbeltswererecognizedinthesouthwesternand northeasternpartofthelakebasin,whichwerenamedasthesouthwestslopebreakbeltandthenortheastslopebreakbeltaccordingly. Theterrainslopewascalculatedwiththerateofformationthicknesschange,andthustheslopebreakpointswereorientatedtoidentify thedistributionofslopebreakbeltsduringtheChang7-Chang6period.Thesouthwesternslopebreakbeltisoflargescale,whilethe northeasternoneissmaller.Theslopebreakbeltsobviouslyhavecontrolsonsandbodies,mainlyreflectedinthreeaspects:origin types,thicknessvariations,anddistributionalmorphology.Uponthedeep-waterslopebreaks,sandbodiesofdeltafrontweredeveloped. However,underthedeep-waterslopebreaks,sandbodieswereformedmostlybygravityflows,suchassublacustrinefanandslump olistolith.Meanwhile,differenttypesofgravityflowssandbodiesdevelopedinsteepslopebeltandgentleslopebelt.Thethicknessofsandbodiesfromthesameprovenancedecreasedfirstlyandthenincreasedfromtheupperslopebreakbelttotheslopetoe.Uponthe slopebreakbelt,sandbodiesoccurinstripsorasasheet.Undertheslopebreakbelt,theirpatternsvariedaccordingtotheterrainslope andthedistancetotheslopetoe.

    ControlsofNeogeneSeaLevelChangeonSandBodies inthePearlRiverMouthBasin
    ZHU Rui,ZHANG Changmin,DU Jiayuan,ZHANG Shangfeng,LI Xiangyang
    2015, 21(4):  685. 
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        DuringtheLateTriassic,theslopebreakbeltofdepressionlakebasinwasdevelopedintheOrdosBasin.Basedontherock types,faciesassociations,andseismicreflectioncharacters,thedeep-waterslopebreakbeltswererecognizedinthesouthwesternand northeasternpartofthelakebasin,whichwerenamedasthesouthwestslopebreakbeltandthenortheastslopebreakbeltaccordingly. Theterrainslopewascalculatedwiththerateofformationthicknesschange,andthustheslopebreakpointswereorientatedtoidentify thedistributionofslopebreakbeltsduringtheChang7-Chang6period.Thesouthwesternslopebreakbeltisoflargescale,whilethe northeasternoneissmaller.Theslopebreakbeltsobviouslyhavecontrolsonsandbodies,mainlyreflectedinthreeaspects:origin types,thicknessvariations,anddistributionalmorphology.Uponthedeep-waterslopebreaks,sandbodiesofdeltafrontweredeveloped. However,underthedeep-waterslopebreaks,sandbodieswereformedmostlybygravityflows,suchassublacustrinefanandslump olistolith.Meanwhile,differenttypesofgravityflowssandbodiesdevelopedinsteepslopebeltandgentleslopebelt.Thethicknessofsandbodiesfromthesameprovenancedecreasedfirstlyandthenincreasedfromtheupperslopebreakbelttotheslopetoe.Uponthe slopebreakbelt,sandbodiesoccurinstripsorasasheet.Undertheslopebreakbelt,theirpatternsvariedaccordingtotheterrainslope andthedistancetotheslopetoe.

    GeochemicalCharacteristicsofSoilsandDiscussiononProspecting intheEukabyLead-ZincExplorationArea,Australia
    DONG Peng, SUN Chuanmin*, XU Guanli, LIU Yansong, TAN Wei, FENG Bo
    2015, 21(4):  694. 
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    BecausehistoricalgeologicalexplorationworkandavailableresearchonEukabylead-zincexplorationarefew,previous prospectingworkhasnotmadeagreatbreakthrough.Inordertoobtainpreliminaryevaluationofprospectingpotentialintheexploration area,soilgeochemicalsurveys(ascaleat1:10000)havebeencarriedout.AccordingtothesoilgeochemicalsurveysinEukaby,the methods of factor analysis, correlation analysis, and cluster analysis from mathematical statistics were applied to investigate the characteristicsofelementcombinationinthisarea.Elementanomaliesweredelineatedbythresholdvaluesofsoilanalysiselements. Thedistributionofelementanomalieswasfoundtobecontrolledbythewelldevelopedjointsandfractures.Themetallogenicmaterials werederivedfromthecontinentalweatheringproductsandwallrocks.AlsotheDelamerianorogenyandsubsequenttectonicactivities providedtheconditionofore-bearingspaceandheatsourceforremobilization,enrichment,andprecipitationofmetalelements.Basedontheanalysisofregionalgeologiccharacteristics,threegeochemicallycomprehensiveanomalousareasweredelineatedinthesoil geochemicalsurveyarea,whichwouldprovidethebasisforfutureexplorationwork.

    TraceandRareEarthElementsandSulfurIsotopeAnalysisofBarite DepositsinWestHunanandEastGuizhou
    SUN Zehang, HU Kai, HAN Shanchu, Liu Yin
    2015, 21(4):  701. 
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    ThebaritedepositsformedintheearlyCambrianinXinhuangandTianzhuarethelargestbaritedepositintheworldandare representativeintheglobalscope.Thisstudycarriedouttherareearthelementsandsulfurisotopeanalysesofthesebaritedeposits.All thesample'sV/CrandU/ThvaluesandtheCenegativeanomalyimpliedthatthedepositswereformedinanaerobicandreduction environment.TherareearthelementsofbaritehaveobviouslyEuelementpositiveanomaly,indicatingthattheore-formingprocesswas stronglyaffectedbytheseafloorhydrothemalfluidandthesourceofthebariumismainlyfromtheseafloorhydrothemalmaterial;The sulfurisotopecompositionofBaSO4mainlyrangedfrom+40‰to+45‰,enrichedin34SandthesulfurisotopeofBaSO4ischaracterized bytowerstyledistribution,whichindicatesthatthesourceofsulfurisofsingle-sourceandfromtheseawatersulfate.Theδ34Sofpyrite islowerthantheδ34Softhecontemporaryseawater,indicatingthatbiologicalbacteriaplayedanimportantroleinthesulfatereduction intheseawaterandimplythatthebaritedepositformedinanenvironmentwherethereislimitedseawaterexchange.Basedontheaboveanalysis,thebaritedepositwasformedinasemiclosed-closedlagoonalandanaerobicenvironmentwheretherearefrequent seafloorhydrothermalactivities.

    StudyonTransformingRelationshipbetweenMagnetiteand Hematite:ACaseStudyonGongchanglingIronDeposit
    FULingzhi,PENGXiaolei*,GAOSong
    2015, 21(4):  711. 
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    Magnetiteandhematitearethetwoformsofironoxidesinnaturalenvironment,andalsothemainoremineralsofthe GongchanglingirondepositinLiaoningprovince,NorthChina.Inthepast,itisgenerallyacceptedthatredoxreactionistheonly processfortheconversionbetweenmagnetiteandhematite.Recently,non-redoxreactiontheorypresentedanalternativetransformation relationshipbetweenmagnetiteandhematitefortheGongchanglingirondeposit.Inthisstudy,withthepolarizationmicroscopeandthe scanningelectronmicroscopybackscattering(BSE)analysis,thestructurecharacteristicsoftheoresamplesfromthedepositwere analyzed,includingthemetasomatismfrommagnetitetohematite,thereplacementofhematitetogoethite,andtheparagenesisamong pyrite,magnetiteandhematite.Throughcharacterizationofmineralassemblages,thestructurecharacteristicsofores,thevolume change of the iron oxides before and after the transformation, we suggest that part of epigenetic hematite which exists in the Gongchanglingirondepositmaybetransformedintheanoxicandreducingenvironmentfrommagnetitethroughthenon-oxidation reaction.Thisprovidesanewexplanationfortheformationmechanismoftheepigenetichematiteinthisirondeposit.

    TheDetritalZirconU-PbGeochronologyandItsProvenance SignificanceofKongtongshanConglomerateDepositsin SouthwesternOrdosBasin
    SHIXiaolin,CHENGang*,YANGFu,ZHANGWenlong,XUXiaogang,LIUTeng,KANGYu,GAOLei
    2015, 21(4):  719. 
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    :Kongtongshanconglomeratedeposits,generallycomposedofKongtongshanFormationandSanqiaoFormation,distributein thePingliangareaofthesouthwesternOrdosBasin.ThestratigraphicageandprovenanceoftheKongtongshanconglomeratehavebeen controversialforalongtime.By usingtheLA-ICP-MSzirconU-Pbisotopegeochronologicmethod,twosamplesofclasticrockswere collectedfromKongtongshanFormationandSanqiaoFormationinthesouthandnorthsidesofKongtongshanpeakstodiscussthesourceandtectonicsignificanceofKongtongshanconglomerate.TheresultsshowthatthedetritalzirconagesoftheUpperTriassic KongtongshanFormationmainlyinclude438~778Ma(n=16),827~1269Ma(n=40),1354~1706Ma(n=16),1826~2080Ma(n=15) and2410~2809Ma(n=17),andthecorrespondingpeakagesare540Ma,995Ma,1660Ma,1930Maand2480Ma.Thedetritalzircon agesoftheLowerCretaceousSanqiaoFormationmainlyinclude281~413Ma(n=6),445~643Ma(n=12),712~1386Ma(n=45),1563~ 1808Ma(n=14),1888~2039Maand(n=10)and2150~2633Ma(n=23),andthecorrespondingpeakagesare335Ma,488Ma,980Ma, 1676Ma,1805Ma,1970Maand2488Ma.ThecomparativeanalysesofzirconU-PbagesshowthatthemainsourcesofKongtongshan Formation and Sanqiao Formation come from the sedimentary rocks, igneous rocks and metamorphic rocks of Pre-Silurian and Pre-PermianfromtheeasternpartofQilianMountainandthewesternpartofNorthQinlingMountainrespectively.Andthereisafew sourcesofthesedimentaryrocksandmetamorphicbasementrocksintheNorthChina(Ordos)oldland.Furthermore,theKongtongshan Formation Conglomerate is composed by the main sources of Qinling Group, Kuanping Group, Dacaotan Group and Caledonian magmaticrocksinthewesternpartoftheNorthQinlingMountain,anditiscontrolledbytheIndosiniantectonismoftheQinlingand QiliancollisionalOrogenicBelts.TheSanqiaoFormationConglomerateiscomposedbythemainsourcesofMaxianshanGroup,Huluhe Group and Caledonian magmatic rocks in the eastern part of Qilian Mountain, and it is controlled by the Qinling and Qilian intracontinentalorogenyduringtheMiddleYanshanintheSouthwesternmarginoftheNorthChina(Ordos).

    MagneticPropertyandMagneticSusceptibilityChangeMechanism oftheXiashuLoessfromZKProfileinZhenjiang,JiangsuProvince
    CHEN Yingyong, LI Xusheng*, HAN Zhiyong, WANG Xiaoyong, LU Huayu
    2015, 21(4):  727.  DOI: 10.16108/j.issn1006-7493.2
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    :A59.4mlongXiashuLoessprofileinZhenjiangwasinvestigated.Magneticpropertiessuchashigh-temperaturemagnetic susceptibility(χ-T)curve,IRMacquisitioncurvesandhysteresisloopsofthisprofilewereanalyzedtoverifythemagneticsusceptibility changemechanism.Theresultsshowthat:1)magneticsusceptibilityvariesgreatlyinthewholeprofileandbetween6.4×10-8m3·kg-1 and186.3×10-8m3·kg-1.Inaddition,thelowerpart(24-59.4m)exhibitslowmagneticsusceptibilitywithanaverageof34.7×10-8m3· kg-1,whichismuchlowerthanthatoftheupperpartof126.1×10-8m3·kg-1;2)allof10representativesamplescanbedividedintotwo groups.Thefirstgroupischaracterizedbyhighmagneticsusceptibility.χ-Tcurvesexhibitobviouscuriepointofmagnetite;IRM acquisitioncurvestendtosaturateat300mT;thereversedemagnetizationcurverevealsacoercivityofremanenceof25-40mT; hysteresisloopsarethinandcloseat600-800mT.Thesefeaturesindicatethatsamplescontainhighabundanceofferrimagnetic minerals (e.g., magnetite, maghemite). The other group has lower magnetic susceptibility; χ-T curves show low initial magnetic susceptibility;IRMacquisitioncurvesarenotsaturatedevenat2.5T;andhaveacoercivityofremanenceof70-135mT.hysteresis loopsdisplayapronouncedwasp-waistedshape.Thesefeaturessuggestthatsamplescontainlittleferrimagneticmineralsandmassive high coercivity minerals (e.g., hematite, goethite), and possibly pyrite; 3) rock magnetic features suggest that the soil-forming environmentchangedwithtime,multi-stagewetenvironmentappearedbefore350kaandresultedinreducingenvironment,magnetite andmaghemiteweretransformedtoweakmagneticminerals,thereforemagneticsusceptibilitywasextremelylow.Thisphenomenonis ingoodagreementwithloessinSiberia;Xiashuloesswascontrolledbyoxidizingenvironmentsince350ka,whichisbeneficialtothe generationoffinemagnetiteandmaghemite,andissimilartotheloessontheChineseLoessPlateau.

    Grain-sizeCharacteristicsofDifferentSedimentaryFaciesfrom theCoreGN100intheEjinaBasin
    ZHANG Chi, WüNNEMANN Bernd, ZENG Lin, ZHANG Hongyan, HAN Zhiyong, YI Shuangwen,
    2015, 21(4):  736.  DOI: 10.16108/j.issn1006-7493.2
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    TheEjinabasin,locatedinthearidareainNWChina,underwentcomplicateddepositionalprocessesduringQuaternary. Basedoncharacteristicsofdifferentsedimentarystructures,a18mlongsedimentcorefromthecenteroftheEjinaBasincanbe divided into fluvial, aeolian, swamp and lacustrine sediments. The grain-size analysis shows that the depositional environment, transportdynamicsintheEjinabasincanbedistinguishedbycharacteristicofgrain-sizedistribution.Themajorgrain-sizecomponent offluvialsedimentwascoarsesandandYvaluewasgreaterthan1;themajorgrain-sizecomponentofaeoliansandwasfinesandandY valuewascloseto0;themajorgrain-sizecomponentofswampsedimentwasalsofinesandbutfinerthanaeoliansand,withanegative Yvalues;themajorgrain-sizecomponentoflacustrinesedimentwasfinesiltwhichwastransportedbysuspension,butdifferentwith settledowndepositinstandingwater,andYvalueswaslessthan-9.Theseresultsshowcharactersofgrainsizedistributioncanbe usedfordistinguishingdifferenttransportprocessesanddynamics,which,inturn,isabletoprovidecriticalinformationforaccurate interpretationofthedepositionalenvironmentchangeinthisarea.

    ReservoirCharacteristicsandFormationMechanismofMLayerin thePaleogeneLowPermeabilityandAlluvialFanReservoirinthe LaojunmiaoOilfield
    YU Chen,WU Shenghe,ZHENG Lianyong,YUE Dali1,ZHANG Shanyan,WANG Xuyi
    2015, 21(4):  747.  DOI: 10.16108/j.issn1006-7493.2
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    Basedonagreatdealofthinsections,cathodoluminescence,electronmicroscopic,corephysicalpropertyandloggingdata,the characteristicsofreservoirandformationmechanismoftheMalluvialfanreservoirinLaojunmiaoOilfield,wasdiscussed,includingthe sedimentarycharacteristicsofreservoir,diagenesisandporosityevolutionwereanalyzed.TheresultsshowthatMreservoirhaverapid accumulation,poorsortingandhighmatrixcontents,itoverallbelongrelativefinealluvialfan.Themainreservoirspaceareintergranular poreswiththecharacteristicsofmediumporosityandlowpermeability.Thedominantdiagenesisinthestudyareahavecompaction, cementationanddenudation.Sedimentationcontrolledtheprimarypores.Thehighmatrixcontentsandpoorsortingresultinthepoorreservoirproperties.ThekindofreservoirisprimarilydistributioninSheetflooddepositionandbraidedriver.Incontrast,thelowmatrix contentsandgoodsortingofthebraided-streambeltreservoirisgreatlyaffectedbycarbonatecement.Carbonatecementfurtherreduce thereservoirphysicalproperties,whichresultinfeaturesoflowpermeableforMreservoir.Thecontentofmatrixandcarbonatecement aremajoraffectingfactorsforlowreservoirphysicalproperty,whichcausethequalitydifferenceanddistributionofreservoir.

    ExperimentalStudyontheGenesisofSecondaryPorosityinTight SandstonewiththeAcidCorrosion-model:ACasefromHe8 MemberofUpperPaleozoicinOrdosBasin
    LIU Ruie, WU Hao*, WEI Xinshan, XIAO Hongping, ZHANG Chunlin, KANG Rui
    2015, 21(4):  758.  DOI: 10.16108/j.issn1006-7493.2
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    Atpresent,anumberofgreatesttightsandstonegasfieldshavebeendiscoveredandprovedintheHe8MemberofOrdos Basin.Thetightsandstonereservoirsmainlyconsistofquartzsandstonewithlowfeldspar,lowmatrix,highcompositionalmaturity.Thetypesofreservoirspacearebasedonmultiplesecondaryerosionpores.Inordertostudytheoriginofvuggyporosityofquartz sandstone,acidolysissimulatingexperimentofopensystem,underthehightemperatureandhighpressureconditions,hasbeen conducted.Meanwhile,theanalysisisbasedonnumerouscastingslices,scanningelectronmicroscope,fieldemissionandCTscan. Experimental samples were selected from the Shihezi Formation of Perimian in Ordos Basin, containing green grey mediumcourse-grainedtuffaceousfeldspathicquartzsandstone,greengreymedium-course-grainedtuffaceousfeldspathiclitharenitesandstone, graymedium-course-grainedtuffaceouslithicquartzsandstoneandgraymedium-course-grainedtuffaceousquartzsandstone.In0.5mol/ Lreactionmediator,2ml/minflowrateanddynamiccorrosionfor100hexperimentalconditions,thesecondaryporosityfordifferent typesofsandstoneincreasedsignificantlyandpropertieswereobviouslyimproved.Bythemeansofisotopescanningofdifferent samplesbeforeandafterexperimentanalysis,thefluid-rockinteractionrateanalysisandplasmaemissionspectrumanalyisis,the authorsindicatethatthemainoriginofthesecondaryporesarethecorrosionoftuffaceous,calcareousandfeldsparmineraletc.The tuffaceous,calcareousoccurerosionundertheconditionoflowtemperature,andfeldsparcorrosionoccurunderhightemperature conditions.Thedevelopmentmechanismoftheerosionoftuffaceous,calcareousandfeldsparmineraletc,poreformationandnew mineralshasbeenrevealed.Combinedwiththeanalysisofburialhistoryandthermalhistory,thediageneticsequencesandporosity evolutionmodeloftightsandstoneofHe8Memberwasputforward.Allthestudiesmakethegenesisofsecondaryporesofquartz sandstoneclearly.