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高校地质学报 ›› 2024, Vol. 30 ›› Issue (01): 12-21.DOI: 10.16108/j.issn1006-7493.2022065

• • 上一篇    下一篇

赤泥基层状双金属氢氧化物合成工艺及应用

姜一梅,沈征涛*   

  1. 南京大学 地球科学与工程学院,南京 210023
  • 出版日期:2024-02-18 发布日期:2024-02-18

Synthesis Technology and Application of Red Mud Based Layered Double Hydroxide

JIANG Yimei,SHEN Zhengtao*   

  1. School of Earth Sciences and Engineering, Nanjing University, Nanjing 210023, China
  • Online:2024-02-18 Published:2024-02-18

摘要: 赤泥是铝土矿炼制氧化铝过程中产生的高碱性废料,随着铝工业的高速发展,世界范围内赤泥年排放量已严重超过环境负荷,造成了巨大的处置压力和污染风险,赤泥的高效资源化利用迫在眉睫。由赤泥制备层状双金属氢氧化物(LDH)是当前国内外重点关注的一个循环路径,具有大规模工业化潜力。文章论述了赤泥基LDH合成工艺及应用研究进展,发现其主要的合成工艺有共沉淀法、煅烧水化法和机械化学合成法,合成的赤泥基LDH类型受铝土矿成分及冶炼工艺影响显著。赤泥基LDH通常被用作吸附剂去除水体无机阴离子及捕获CO2,同时也是一种新型环保型无卤阻燃添加剂。赤泥基LDH还是一种优异的光催化剂,赤泥中杂质(Fe2O3)的引入导致局部构筑异质结构,有利于光敏电子和空穴物种的分离与传递。最后文章提出如下展望:(1)在双碳目标背景下,赤泥基LDH的制备符合“循环经济”等可持续发展目标,具有实际的大规模应用潜力,未来应大力推进合成及应用方面的研究;(2)未来应重点研究如何进一步优化合成工艺,提高产率,增强可持续性(如引入其他废弃物作为二价金属源),提高合成专一性,以及如何降低赤泥基LDH在应用过程中的环境风险;(3)明晰LDH结构与应用效果的“构效关系”,针对赤泥基LDH非纯净体系这一特性,扬长避短,发挥异质结构的优势,实现更高效的应用。

关键词: 赤泥, 层状双金属氢氧化物(LDH), 吸附, 催化, 阻燃

Abstract: Red mud is a highly alkaline waste produced in the process of refining alumina from bauxite. Due to the rapid development of the aluminum industry, the annual discharge of red mud in the world has seriously exceeded the environmental load, resulting in huge disposal pressure and pollution risks. Therefore, the efficient utilization of red mud as a resource is imminent. The preparation of layered double hydroxide (LDH) from red mud is a circulating route, and has the potential for large-scale industrialization. This paper reviews the research progress of red mud based LDH synthesis technology and application. It is found that the main synthesis processes include co-precipitation, calcination-hydration and mechanochemical methods. The synthesized red mud-based LDH type is affected by bauxite composition and smelting technology. Significant impact. Red mud based LDH is typically used as an absorbent to remove inorganic pollutants and capture CO2, and it is also a new environmentally friendly halogen-free flame retardant additive. Red mud based LDH is also an excellent photocatalyst, and the introduction of impurities(Fe2O3) in red mud leads to the local construction of heterostructures, which is beneficial to the separation and transfer of photosensitive electrons and holes. Finally, this paper puts forward the following prospects: (1) In the context of carbon neutral targets, the preparation of red mud based LDH meets the sustainable development goals such as “circular economy” and has practical potential for large-scale

application, and the synthesis and application research should be vigorously promoted; (2) It should focus on how to further optimize the synthesis process, improve yield, enhance sustainability (such as introducing other wastes as divalent metal sources), improve synthesis specificity, and reduce the environmental risk of red mud-based LDH in the application process; (3) Understand the relationship between LDH properties and its performance, and exploit the advantages of the heterostructure of red mud based LDH achieve a more efficient a pplication.

Key words: red mud, layered double hydroxide (LDH), absorption, catalysis, flame retardant

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