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J4 ›› 2011, Vol. 17 ›› Issue (4): 492-512.

• 岩石学与矿床学 • 上一篇    下一篇

浙东南晚中生代玄武岩的地球化学特征及其对源区物质的指示意义

崔玉荣, 谢 智, 王 斌, 陈江峰, 俞云文, 贺剑锋    

  1. 1. 中国科学技术大学 地球和空间科学学院,中科院 壳幔物质与环境重点实验室,合肥 230026;
    2. 天津地质矿产研究所,天津 300170;3. 浙江省地调院,萧山 311200
  • 收稿日期:2011-08-02 修回日期:2011-09-26 出版日期:2011-12-20 发布日期:2011-12-20
  • 作者简介:崔玉荣,女,助理工程师,地球化学专业;E-mail:cyr007@mail.ustc.edu.cn
  • 基金资助:

    中科院知识创新项目(KZCX2-EW-QN508,KZCX2-YW-Q08-3-3);

    国家自然科学基金项目(40873002,40673008)和新世纪优
    秀人才支持计划(NCET-07-0795)共同资助

Geochemical Characteristics of the Late Mesozoic Basalts in Southeastern Zhejiang Province and Constraints on Magma Source Materials

CUI Yu-rong, XIE Zhi, WANG Bin, CHEN Jiang-feng, YU Yun-wen, HE Jian-feng    

  1. 1. Chinese Academy of Sciences Key Laboratory of Crust Mantle Materials and Environments, School of Earth and Space Sciences,
    University of Science and Technology of China, Hefei 230026, China;
    2. Tianjin Institute of Geology and Mineral Resources, Tianjin 300170, China;
    3. Zhejiang Geological Survey, Xiaoshan 311200, China
  • Received:2011-08-02 Revised:2011-09-26 Online:2011-12-20 Published:2011-12-20
  • About author:Cui Yurong, Assistant Enqineer; E-mail: cyr007@mail.ustc.edu.cn

摘要:

浙江东南部晚中生代上、下火山岩系(以下简称上、下岩系)中均有玄武岩产出,本文对这些玄武岩分别进行了元
素地球化学和Sr-Nd-Pb同位素研究。不同岩系玄武岩的主量元素均表现出富碱、富Al等特征。但微量元素存在差异,下岩
系天台和青田样品具有轻稀土富集以及Ba, Pb和Sr富集,Eu负异常,Nb, Ta, Zr和Hf亏损的特征。上岩系玄武岩的元素特征
也有差别,永嘉花坦、宁波玄坛地、新昌镜岭和永嘉镜架山等地样品的元素特征表现出的性质与下岩系样品相似,武义玄
武岩样品没有Ta, Nb亏损特征,金衢盆地玄武岩的元素特征则介于两者之间。对应的,这些玄武岩样品的同位素组成也有
明显差异,下岩系玄武岩的初始同位素组成范围为 I Sr=0.70850~0.70897,εN(d t) = -5.6~-4.1,(206Pb/204Pb) i =18.21~18.38,(207Pb/204Pb) i =15.55~15.58,(208Pb/204Pb) i =38.26~38.49,接近下岩系中酸性岩浆岩的范围,反映了下地壳物质对其岩浆源区的显著影响。上岩系玄武岩有明显差异,表现出与元素特征对应的分组现象。其中永嘉花坦、宁波玄坛地、新昌镜岭和永嘉镜架山样品 I Sr = 0.70734~0.70936, εN(d t)= -7.1~-2.1,( 206Pb/204Pb) i =18.01~18.40,( 207Pb/204Pb) i = 15.54~15.62,( 208Pb/204Pb) i=37.99~38.62, 具有富集特征, 可能来自活动大陆边缘; 而武义和金衢盆地样品的 I Sr=0.70533~0.70589, εNd( t) =0.4~3.3,(206Pb/204Pb) i =17.23~18.11,( 207Pb/204Pb) i =15.46~15.53,( 208Pb/204Pb) i =36.91~38.43,具有类似OIB特征,趋向亏损地幔端元。上下岩系玄武岩的元素和同位素组成的研究表明,玄武岩的物质来源有较明显的差别,且表现出随时间变化的特征。其中下岩系玄武岩源区中可能有古老岩石圈地幔、下地壳物质和俯冲蚀变洋壳物质的贡献,而上岩系中玄武岩源区有可能是类似下岩系玄武岩性质的岩石圈、软流圈地幔和下地壳物质等的贡献。浙东南晚中生代岩石圈演化的动力学过程可能与太平洋板块俯冲有关,但不能排除岩石圈地幔拆沉的影响,具体的讨论还需要更多的岩石学和/或地幔包体资料的补充。

关键词: 晚中生代;玄武岩;地球化学特征;源区物质;浙东南

Abstract:

The late Mesozoic basalts occur in the southeastern Zhejiang Province together with acidic volcanic rocks, which can be divided into upper and lower rock series (URS and LRS). Major, trace elements and Sr-Nd-Pb isotopic features of these basalts are studied in this paper to provide insights into the nature of their magma sources and evolution processes. Both the
URS and LRS basalts are enriched in alkaline and Al elements. However, their characteristics of trace elements are different.
The samples from Tiantai and Qingtian of LRS are enriched in LREEs, Ba, Pb and Sr, and depleted in Nb, Ta, Zr and Hf with Eu
negative anomalies. The basalts from Yongjiahuatan, Ningboxuantandi, Xinchangjingling and Yongjiajingjiashan basalts of URS
show similar trace elements and REEs natures to those of the samples from LRS, but basalts from Wuyi of URS show no negative Ta, Nb anomalies, while the trace element features of the basalts from Jinqu Basin are on the average. Correspondingly, isotopic compositions of these basalts are also variable apparently. The initial isotopic ratios of basalts from LRS range are as follows: ISr= 0.70850~ 0.70897, εNd(t )=-5.6~-4.1, (206Pb/204Pb)i =18.21~18.38, (207Pb/204Pb)i =15.55~15.58, (208Pb/204Pb)i =38.26~38.49,which are approximate to those of the intermediate-acid magmatic rocks in LRS, indicating that their magmatic sources were contaminated significantly by the lower crustal materials. Basalts from URS demonstrate a marked difference from those of the LRS in isotopic features by showing similar groups as the characteristics of trace elements. The samples from Yongjiahuatan,Ningboxuantandi, Xinchangjingling and Yongjiajingjiashan of URS have enriched Sr-Nd isotopic compositions with I Sr=0.70734~0.70936, εNd(t )=-7.1~-2.1, (206Pb/204Pb)i =18.01~18.40, (207Pb/204Pb)i =15.54~15.62, (208Pb/204Pb)i = 37.99~38.62,suggesting that these basalts are most likely generated from active continental margin. The samples from Wuyi and Jinqu Basins have the characteristics similar to OIB with I Sr = 0.70533~0.70589, εNd(t ) = 0.4~3.3, (206Pb/204Pb)i = 17.23~18.11, (207Pb/204Pb)i=15.46~15.53, (208Pb/204Pb)i = 36.91~38.43, towards the end member of depleted mantle. Based on elements and isotopic compositions of the Late Mesozoic basalts from the southeastern Zhejiang Province, the sources of the basalt are significantlydifferent and varied obviously with time. It could be concluded that the initial magma of basalts of LRS may be derived fromthe ancient lithospheric mantle, subducted altered oceanic crust and contaminated by lower crustal materials. The source of the basalts of URS may contain the materials of the lithospheric mantle which is similar to basalts from LRS, depleted OIB-like mantle and lower crust materials. It is also concluded the formation of the late Mesozoic basalts in the southeastern Zhejiang Province may be related to the Pacific plate subduction, but the influence of delamination of the lithospheric mantle could not be ruled out.Since that, much further information of petrology and/or mantle xenoliths is needed for the specific discussion about the dynamic process.

Key words: late Mesozoic, basalts, geochemical characteristics, source material, southeastern Zhejiang Province

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