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高校地质学报 ›› 2026, Vol. 32 ›› Issue (05): 624-638.DOI: 10.16108/j.issn1006-7493.2025058

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南非西格里夸兰地区条带状铁建造的矿物学研究及成因指示

方 舟,袁余丽,黄启琳,张 贺,徐靖博,蔡元峰*   

  1. 关键地球物质循环与成矿全国重点实验室, 南京大学 地球科学与工程学院,南京 210023
  • 出版日期:2026-10-20 发布日期:2026-10-20

Mineralogical and Diagenetic Study of Banded Iron Formation from Griqualand West in South Africa

FANG Zhou,YUAN Yuli,HUANG Qilin,ZHANG He,XU Jingbo,CAI Yuanfeng*   

  1. National Key Laboratory of Earth Material Cycling and Mineralization, School of Earth Sciences and Engineering,
    Nanjing University, Nanjing 210023, China
  • Online:2026-10-20 Published:2026-10-20

摘要: 前寒武纪的两次大气增氧事件既改造了地球的表层系统,也为生命演化创造了适宜环境。全球范围内大规模前寒武
纪条带状铁建造(Banded Iron Formation, BIF)的形成是对表层系统变化的沉积响应,也是理解前寒武纪地质环境和演化过程的重要载体。文章针对南非西格里夸兰(Griqualand West)地区BIF,利用X射线衍射(X-Ray diffratometry, XRD)、扫描电子显微术(Scanning Electron Microscopy, SEM)等技术手段,开展了较精细的观察、分析与研究,揭示其矿物组成、形成环境和成因机制。研究表明,南非西格里夸兰地区BIF主要由赤铁矿、磁铁矿、菱铁矿和针铁矿等铁矿物和(铁)白云石、方解石、石英(含燧石)、菱锰矿、软锰矿等非铁矿物组成,含铁矿物颗粒一般呈极为自形的形貌特征。上述铁矿物和非铁矿物构成了矿物组成不同、厚度不一的铁质或硅质条带,条带厚度从厘米级到微米级均有,包括厚约50~250 μm的极薄微条带。铁质和硅质条带形态平直,近平行、韵律性分布,暗示了形成环境的Eh和pH的规律性变化、物源的亿年尺度的稳定性。此外,样品的SEM-EDS面扫结果显示既有单质碳存在,还显示了铁、锰、碳的耦合分布,这暗示BIF的形成可能有微生物的贡献。

关键词: 元古代, 矿物组成, 岩石结构, 条带状铁建造

Abstract: The two oxygenation events in the Precambrian were not only continuously rebuilding Earth’s surficial system but also fostering the evolution of habitable environment for life. The globally distribution of banded iron formations (BIFs) respond to the changes of surficial system. BIFs also record abundand information regarding the evolution of the atmosphere, lithosphere, hydrosphere, and biosphere. They are of great scientific significance, as they provide a crucial window for understanding Precambrian geological environments and evolutionary characteristics. This study focuses on the BIFs in the Griqualand West region, South Africa, and utlizes techniques including X-ray diffractometry, SEM equipped with EDS etc, to conduct a detailed mineralogical investigation. We aim to constrain the mineral assemblages, formation conditions, and genesis of the BIFs. The results show that the BIF consists of iron minerals including hematite, magnetite, siderite, goethite, as well as non-iron minerals such as quartz, calcite, rhodochrosite, and rhodonite. These minerals are composed of nanosized grains and occur as granular or oolitic particles. The BIFs display extremely fine banded laminaes, generally 50-250 μm in thickness. These bands comprise alternating layers dominated by iron-rich minerals and chert or silicate-rich minerals, deposited sub-parallel to one another. Irrespective of grain size, numerous iron-bearing mineral grains show well-developed euhedral morphologies, frequently with banded zoning textures. SEM-EDS mapping reveals the native carbon grains and coupled Fe-Mn-C distributions, which may point to a microbial role in the formation of the BIFs.

Key words: Paleoproterozoic, mineral compostion, texture, Banded Iron Formation

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