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高校地质学报 ›› 2024, Vol. 30 ›› Issue (05): 514-525.DOI: 10.16108/j.issn1006-7493.2023048

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南疆铁门关土壤白云石与氟元素的耦合关系

沈 泽1,何峻岭2,段星星2,朱晓雨1,王若水1,季峻峰1,刘连文1*   

  1. 1. 南京大学 地球科学与工程学院,表生地球化学教育部重点实验室,南京 210023;
    2. 中国地质调查局 乌鲁木齐自然资源综合调查中心,乌鲁木齐 835700
  • 出版日期:2024-10-20 发布日期:2024-10-20

Coupling Relationship Between Dolomite and Fluorine in the Soil of Tiemenguan, Xinjiang

SHEN Ze1,HE Junling2,DUAN Xingxing2,ZHU Xiaoyu1,WANG Ruoshui1,JI Junfeng1,LIU Lianwen1*   

  1. 1. MOE Key Laboratory of Surficial Geochemistry, Department of Earth Sciences, Nanjing University, Nanjing 210023, China;
    2. Center of Urumqi Natural Resources Comprehensive Survey, China Geological Survey, Urumqi 830057, China
  • Online:2024-10-20 Published:2024-10-20

摘要: 南疆环塔里木盆地的绿洲土壤发育了大量的碳酸盐矿物,同时该地区土壤和地下水的氟(F)元素含量较高,存在较大的F污染风险。探讨两者的耦合关系,对开展干旱区土壤无机碳汇的综合利用、提高区域F污染的防治水平有重要意义。文章选择新疆铁门关市15个典型表层土壤,通过XRD、扫描电镜等分析手段对土壤样品进行测试,同时分析常量、微量元素和碳酸盐Sr同位素组成,并结合室内选择性溶解实验方法,对该地区土壤矿物学与地球化学特征进行了系统研究,获得了F与碳酸盐矿物耦合变化机制的地质证据。研究发现,铁门关地区土壤中矿物组成较为复杂,其主要元素含量接近于上部大陆地壳,化学风化指数CIA值在50~60之间,风化程度较弱。土壤中含较高的方解石和白云石等碳酸盐矿物(平均含量为20.1%),碳酸盐平均Sr, Mn含量分别为1434×10-6和1736×10-6,87Sr/86Sr比值为0.710左右。土壤中F与碳酸盐矿物有关的元素高度正相关,并且与白云石呈现很好的耦合变化。推测土壤中的F异常主要来自源区的氟镁石,在地质、气候等综合因素下共同迁移变化。

关键词: 南疆, 土壤, 氟, 白云石, 碳酸盐矿物

Abstract: The oasis soil around the Tarim Basin in southern Xinjiang has developed a large amount of carbonate minerals, meanwhile the regional fluorine content in soil and groundwater is high, which poses a huge risk of fluorine pollution. Exploring the coupling relationship between the two is significant for comprehensive utilization of soil inorganic carbon sinks in arid regions and improving the prevention and control of regional fluoride pollution. This study sampled 15 typical surface soils from Tiemenguan, Xinjiang, and conducted a systematic study on the mineralogical and geochemical characteristics of the samples, using XRD, scanning electron microscopy, and other instrumental analysis methods. With the major and trace element content as well as carbonate Sr isotope compositions analyzed, combined with indoor selective dissolution experiments, geological evidence for the coupling mechanism of fluoride and carbonate minerals were obtained. Our study found that the mineral composition of the soil from Tiemenguan is relatively complex, with the major element content similar to that of the upper continental crust (UCC) and the chemical weathering index (CIA) value between 50 and 60 which indicates a relatively weak weathering. The soil contains a relatively large portion of carbonate minerals such as calcite and dolomite, with average Sr and Mn contents of 1434 ppm and 1736 ppm, respectively, and a 87Sr/86Sr ratio of 0.710. Fluorine in soil is highly correlated with elements related to carbonate minerals, and exhibits a good coupling relationship with dolomite. It is speculated that the fluorine anomaly in the soil mainly comes from the magnesium fluorite in the source area, which is subject to combined migration with dolomite due to geological and climatic factors.

Key words: Southern Xinjiang, soil, fluorine, dolomite, carbonate minerals

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